deacetylpseudolaric acid A

Base Information

Chemical Name:deacetylpseudolaric acid A
CAS No.:82508-37-0
Molecular Formula:C₂₀H₂₆O₅
Molecular Weight:346.423
Hs Code.:
DSSTox Substance ID:DTXSID401311131
Nikkaji Number:J2.374.446E
Wikidata:Q105170150
ChEMBL ID:CHEMBL222903

Synonyms:deacetylpseudolaric acid A;82508-37-0;(2E,4E)-5-[(1R,7S,8R,9R)-7-hydroxy-4,9-dimethyl-11-oxo-10-oxatricyclo[6.3.2.01,7]tridec-3-en-9-yl]-2-methylpenta-2,4-dienoic acid;CHEMBL222903;DTXSID401311131;1H-4,9a-Ethanocyclohepta[c]pyran, 2,4-pentadienoic acid deriv.;(-)-Deacetylpseudolaric acid A;HY-N3696;AKOS040760364;FS-9074;CS-0024077

Suppliers and Price of deacetylpseudolaric acid A

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
DeacetylpseudolaricacidA 95+%
5mg
$ 810.00

AvaChem
Deacetylpseudolaric acid A
5mg
$ 290.00

AvaChem
Deacetylpseudolaric acid A
1mg
$ 119.00

AvaChem
Deacetylpseudolaric acid A
20mg
$ 690.00

AvaChem
Deacetylpseudolaric acid A
10mg
$ 490.00

Arctom
DeacetylpseudolaricacidA ≥98%
5mg
$ 398.00

Total 22 raw suppliers

Chemical Property of deacetylpseudolaric acid A

Chemical Property:

Boiling Point:569.38 °C at 760 mmHg
Flash Point:202.266 °C
Density:1.249 g/cm³
XLogP3:2.1
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:346.17802393
Heavy Atom Count:25
Complexity:703

Purity/Quality:

98%min ^*data from raw suppliers

DeacetylpseudolaricacidA 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CCC23CCC(C2(CC1)O)C(OC3=O)(C)C=CC=C(C)C(=O)O
Isomeric SMILES:CC1=CC[C@]23CC[C@H]([C@]2(CC1)O)[C@@](OC3=O)(C)/C=C/C=C(\C)/C(=O)O

Technology Process of deacetylpseudolaric acid A

There total 13 articles about deacetylpseudolaric acid A which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

: 82508-32-5
pseudolaric acid A

: 82508-37-0
deacetylpseudolaric acid A

Guidance literature:: With methanol; potassium hydroxide; at 20 ℃; for 12h;
DOI:10.1016/j.bioorg.2021.104963

Reference yield:

: 5-(7-hydroxy-4,9-dimethyl-11-oxo-10-oxa-tricyclo[6.3.2.0^1,7]tridec-3-en-9-yl)-2-methyl-penta-2,4-dienoic acid 2-methoxy-ethoxymethyl ester

: 82508-37-0
deacetylpseudolaric acid A

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; at 20 ℃; for 7h;
DOI:10.1002/anie.200602056

Reference yield:

: 4-(diethoxy-phosphoryl)-2-methyl-but-2-enoic acid 2-methoxy-ethoxymethyl ester

: 82508-37-0
deacetylpseudolaric acid A

Guidance literature:: Multi-step reaction with 4 steps

1: n-BuLi / tetrahydrofuran; hexane / 0 - 20 °C

2: aq. AcOH / 0.5 h / 60 °C

3: Dess-Martin periodinane / CH₂Cl₂ / 1 h / 20 °C

4: aq. HCl / tetrahydrofuran / 7 h / 20 °C

With hydrogenchloride; n-butyllithium; Dess-Martin periodane; acetic acid; In tetrahydrofuran; hexane; dichloromethane; 1: Horner-Emmons reaction / 3: Dess-Martin oxidation;
DOI:10.1002/anie.200602056