Pterodondiol

Base Information

• Chemical Name: Pterodondiol
• CAS No.: 60132-35-6
• Molecular Formula: C15H28O2
• Molecular Weight: 240.38200
• Mol file: 60132-35-6.mol

Synonyms:

Chemical Property of Pterodondiol

Chemical Property:

• PSA: 40.46000
• LogP: 3.11480

Purity/Quality:

99% ^*data from raw suppliers

Pterodondiol >98%,StandardReferencesGrade ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Pterodondiol

There total 30 articles about Pterodondiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

selin-11-en-4α-ol (37519-31-6) + methyllithium (917-54-4) → cryptomeridiol (60132-35-6,92857-25-5,108006-39-9,122674-21-9,143004-65-3,4666-84-6,55353-16-7)

Guidance literature:

selin-11-en-4α-ol; methyllithium; In diethyl ether; at -10 ℃; for 1h;

With hydrogenchloride; In diethyl ether; water;

DOI:10.1016/j.tetlet.2011.05.064

Reference yield: 100.0%

(1S,4aR,7R,8aS)-7-(1-Hydroxy-1-methyl-ethyl)-1,4a-dimethyl-1,4,4a,5,6,7,8,8a-octahydro-naphthalen-1-ol (198994-54-6) → (2R)-pterodondiol (60132-35-6,55353-16-7)

Guidance literature:

With hydrogen; Pd/SrCO₃; In ethyl acetate; for 3h; under 760 Torr;

DOI:10.1021/np9702906

Reference yield: 81.0%

11-acetoxyeudesman-4α-ol → cryptomeridiol (60132-35-6,92857-25-5,108006-39-9,122674-21-9,143004-65-3,4666-84-6,55353-16-7)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 1.5h; Ambient temperature;

DOI:10.1248/cpb.44.1603

upstream raw materials:

elemol

eudesmagnolol

eudeshonokiol A

2-[(2R,4aR,8R,8aR)-8-(3,5'-Diallyl-2'-methoxy-biphenyl-4-yloxy)-4a,8-dimethyl-decahydro-naphthalen-2-yl]-propan-2-ol

Downstream raw materials:

intermedeol

Refernces

• 1、 Shimoma, Fumito,Kondo, Hisao,Yuuya, Saori,Suzuki, Toshio,Hagiwara, Hisahiro,Ando, Masayoshi. "Enantioselective total syntheses of (-)-7βH-eudesmane-4α,11-diol and (+)-ent-7βH-eudesmane-4α,11-diol". . p. 22 - 28. Retrieved 2007/10/03.
• 2、 Piet, Dennis P.,Minnaard, Adriaan J.,Heyden, Karel A. van der,Franssen, Maurice C. R.,Wijnberg, Joannes B. P. A.,Groot, Aede de. "Biotransformation of (+/-)-4,8-dimethylcyclodeca-3(E),7(E)-dien-1β-ol and (+)-Hedycaryol by Cichorium intybus". . p. 243 - 254. Retrieved 2007/10/02.