(E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol

Base Information

Chemical Name:(E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol
CAS No.:692749-36-3
Molecular Formula:C₄₀H₇₆O₆Si₃
Molecular Weight:737.296
Hs Code.:

(E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol

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Chemical Property of (E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol

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Technology Process of (E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol

There total 6 articles about (E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 220213-54-7
(E)-(R)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-pent-2-en-1-ol

: 692749-36-3
(E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol

Guidance literature:: Multi-step reaction with 10 steps

1: 95 percent / 2-iodylbenzoic acid

2: 93 percent / Bu₂BOTf; Et₃N

3: LiBH₄

4: 95 percent / OsO₄; 4-methylmorpholine 4-oxide

5: 84 percent / NaIO₄

6: 99 percent / Bu₂BOTf; Et₃N

7: LiBH₄

With sodium periodate; osmium(VIII) oxide; lithium borohydride; di-n-butylboryl trifluoromethanesulfonate; 2-iodoxybenzoic acid; 4-methylmorpholine N-oxide; triethylamine; 2: Evans aldol reaction / 8: Evans aldol reaction;
DOI:10.1002/anie.200353348

Reference yield:

: 692749-33-0
(S)-3-[(E)-(2S,3S,6R)-3-Hydroxy-7-(4-methoxy-benzyloxy)-4,6-dimethyl-2-vinyl-hept-4-enoyl]-4-isopropyl-oxazolidin-2-one

: 692749-36-3
(E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol

Guidance literature:: Multi-step reaction with 8 steps

1: LiBH₄

2: 95 percent / OsO₄; 4-methylmorpholine 4-oxide

3: 84 percent / NaIO₄

4: 99 percent / Bu₂BOTf; Et₃N

5: LiBH₄

With sodium periodate; osmium(VIII) oxide; lithium borohydride; di-n-butylboryl trifluoromethanesulfonate; 4-methylmorpholine N-oxide; triethylamine; 6: Evans aldol reaction;
DOI:10.1002/anie.200353348

Reference yield:

: 692749-34-1
1-[(E)-(2R,5S,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2,4-dimethyl-octa-3,7-dienyloxymethyl]-4-methoxy-benzene

: 692749-36-3
(E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / OsO₄; 4-methylmorpholine 4-oxide

2: 84 percent / NaIO₄

3: 99 percent / Bu₂BOTf; Et₃N

4: LiBH₄

With sodium periodate; osmium(VIII) oxide; lithium borohydride; di-n-butylboryl trifluoromethanesulfonate; 4-methylmorpholine N-oxide; triethylamine; 3: Evans aldol reaction;
DOI:10.1002/anie.200353348