([κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methylpalladium(II))2(N,N,N',N'-tetramethylethylenediamine)

Base Information

• Chemical Name: ([κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methylpalladium(II))2(N,N,N',N'-tetramethylethylenediamine)
• CAS No.: 1107629-43-5
• Molecular Formula: C₄₈H₅₈N₂O₁₀P₂Pd₂S₂
• Molecular Weight: 1161.92
• Mol file: 1107629-43-5.mol

Synonyms:

Chemical Property of ([κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methylpalladium(II))2(N,N,N',N'-tetramethylethylenediamine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ([κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methylpalladium(II))2(N,N,N',N'-tetramethylethylenediamine)

There total 1 articles about ([κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methylpalladium(II))2(N,N,N',N'-tetramethylethylenediamine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II) + 2-{bis(2-methoxyphenyl)phosphino}benzenesulphonic acid (257290-43-0) → ([κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methylpalladium(II))2(N,N,N',N'-tetramethylethylenediamine) (1107629-43-5)

Guidance literature:

In tetrahydrofuran; under inert atmosphere; ligand reacted with Pd complex in THF at room temp.; according to K. M. Skupov et al., Macromolecules, 2006, 39, 4279;

DOI:10.1021/om9003225

Reference yield: 95.0%

tris-(2-sulfophenyl)phosphine trisodium salt + ([κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methylpalladium(II))2(N,N,N',N'-tetramethylethylenediamine) (1107629-43-5) → [κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methyl(sodium tri(m-sulfonatophenyl)phosphine)palladium(II)

Guidance literature:

In N,N-dimethyl-formamide; uncder Ar; DMF added to mixt. of Pd complex and ligand at 20°C with stirring; stirred for 1 h; solvent removed under vac.; washed with CH2Cl2 and Et2O; dried under vac.; elem. anal.;

DOI:10.1021/om9003225

Reference yield: 91.0%

([κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methylpalladium(II))2(N,N,N',N'-tetramethylethylenediamine) (1107629-43-5) + NH2(CH2CH2O)52CH3 → [κ2-P,O-2-(di(2-methoxyphenyl)phosphino)benzenesulfonato]methylpalladium(II)(NH2(CH2CH2O)54Me)

Guidance literature:

In N,N-dimethyl-formamide; uncder Ar; DMF added to mixt. of Pd complex and ligand at 20°C with stirring; stirred for 1 h; solvent removed under vac.; washed with Et2O; dried under vac.; elem. anal.;

DOI:10.1021/om9003225

upstream raw materials:

2-{bis(2-methoxyphenyl)phosphino}benzenesulphonic acid