W(S)(C₆H₅C₂C₆H₅)(S₂CN(C₂H₅)2)(SCN(C₂H₅)2)

Base Information

Chemical Name:W(S)(C₆H₅C₂C₆H₅)(S₂CN(C₂H₅)2)(SCN(C₂H₅)2)
CAS No.:94706-53-3
Molecular Formula:C₂₄H₃₀N₂S₄W
Molecular Weight:658.63
Hs Code.:

W(S)(C<sub>6</sub>H<sub>5</sub>C<sub>2</sub>C<sub>6</sub>H<sub>5</sub>)(S<sub>2</sub>CN(C<sub>2</sub>H<sub>5</sub>)2)(SCN(C<sub>2</sub>H<sub>5</sub>)2)

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Chemical Property of W(S)(C₆H₅C₂C₆H₅)(S₂CN(C₂H₅)2)(SCN(C₂H₅)2)

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Technology Process of W(S)(C₆H₅C₂C₆H₅)(S₂CN(C₂H₅)2)(SCN(C₂H₅)2)

There total 3 articles about W(S)(C₆H₅C₂C₆H₅)(S₂CN(C₂H₅)2)(SCN(C₂H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 286-28-2
cyclohexene sulfide

: 73848-23-4,94799-48-1
(W(CO)(C₂(C₆H₅)2)(S₂CN(C₂H₅)2)2)

: W(S)(C₆H₅CCC₆H₅)(S₂CN(CH₂CH₃)2)2

: 94706-53-3
W(S)(C₆H₅C₂C₆H₅)(S₂CN(C₂H₅)2)(SCN(C₂H₅)2)

Guidance literature:: In toluene; byproducts: CO, C6H10; inert atmosphere, soln. of the W-complex and 1 equivalent of C6H10S refluxed for 10 min; cooled, volume reduced in vacuo, chromd. on Florisil with toluene and toluene/CH2Cl2 (1:1), reduced in vacuo, crystallizations induced by cooling a CH2Cl2/hexane soln. to -20°C, elem. anal.;
DOI:10.1021/om00123a022

Reference yield:

: W(S)(C₆H₅CCC₆H₅)(S₂CN(CH₂CH₃)2)2

: 94706-53-3
W(S)(C₆H₅CCC₆H₅)(SCN(CH₂CH₃)2)(S₂CN(CH₂CH₃)2)

Guidance literature:: With triethylphosphine; In dichloromethane; byproducts: triethylphosphine sulphide; a CH2Cl2 soln. of 1 eqiuv of PEt3 was added to a CH2Cl2 soln. of W-complex at -78°C under N2 (Schlenk tube), mixt. was stirred for 90 min and permitted to warm slowly to room temp.; solvent was removed under vac., residue dissolved in toluene and chromd. on a Florisil column (eluent toluene), eluate was evapd., residue triturated with hexane, crystd. from CH2Cl2-hexane at -20°C;