Technology Process of lithium tert-butyltris(3-phenylpyrazol-1-yl)borate
There total 1 articles about lithium tert-butyltris(3-phenylpyrazol-1-yl)borate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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byproducts: H2; (Ar, Schlenk) the mixt. of Li-compound and pyrazole was stirred and heated, first at 120°C until H2 evolution (1 h), then at 220°Cuntil H2 evolution stopped (12 h), cooled to room temp.; an excess of pyrazole-compound was removed under a vac. at 170°C (8 mm Hg), the solid was ground, ppt. was stirred in hexane, filtered, dried in vac.;
DOI:10.1021/ic060458n
- Guidance literature:
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In
methanol; water;
(Ar, Schlenk) an aq. TlNO3 (1.1 equiv) was added to a soln. of Li-compound in methanol; ppt. was filtered, washed with methanol, dried in vac.; elem. anal.;
DOI:10.1021/ic060458n
