methyl 2-(4-bromo-2-methyl-6-nitrophenoxy)acetate

Base Information

Chemical Name:methyl 2-(4-bromo-2-methyl-6-nitrophenoxy)acetate
CAS No.:943994-74-9
Molecular Formula:C10H10BrNO5
Molecular Weight:304.09400
Hs Code.:2918990090
Mol file:943994-74-9.mol

Synonyms:FD7269;methyl (4-bromo-2-methyl-6-nitrophenoxy)acetate;

Suppliers and Price of methyl 2-(4-bromo-2-methyl-6-nitrophenoxy)acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Methyl2-(4-bromo-2-methyl-6-nitrophenoxy)acetate 95+%
5g
$ 719.00

Crysdot
Methyl2-(4-bromo-2-methyl-6-nitrophenoxy)acetate 95+%
1g
$ 179.00

Alichem
Methyl2-(4-bromo-2-methyl-6-nitrophenoxy)acetate
1g
$ 172.11

Total 9 raw suppliers

Chemical Property of methyl 2-(4-bromo-2-methyl-6-nitrophenoxy)acetate

Chemical Property:

PSA：81.35000
LogP:2.74070
Storage Temp.:Sealed in dry,Room Temperature

Purity/Quality:

97% ^*data from raw suppliers

Methyl2-(4-bromo-2-methyl-6-nitrophenoxy)acetate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl 2-(4-bromo-2-methyl-6-nitrophenoxy)acetate

There total 1 articles about methyl 2-(4-bromo-2-methyl-6-nitrophenoxy)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 20294-50-2
4-bromo-2-methyl-6-nitrophenol

: 96-32-2
bromoacetic acid methyl ester

: 943994-74-9
methyl (4-bromo-2-methyl-6-nitrophenoxy)acetate

Guidance literature:: With potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 48h;
DOI:10.1016/j.bmc.2014.07.038

Reference yield: 70.0%

: 943994-74-9
methyl (4-bromo-2-methyl-6-nitrophenoxy)acetate

: 121564-97-4
6-bromo-8-methyl-2H-1,4-benzoxazin-3(4H)-one

Guidance literature:: With acetic acid; zinc; In tetrahydrofuran; at 45 ℃; for 1.5h; Reflux;
DOI:10.1016/j.bmc.2014.07.038

Reference yield:

: 943994-74-9
methyl (4-bromo-2-methyl-6-nitrophenoxy)acetate

: 6-[1-(4-fluoro-2-methylphenyl)-3-(trifluoromethyl)-1H-pyrazol-5-yl]-8-methyl-2H-1,4-benzoxazin-3(4H)-one

Guidance literature:: Multi-step reaction with 4 steps

1: acetic acid; zinc / 12 h / 100 °C

2: dichlorobis(tri-O-tolylphosphine)palladium; potassium carbonate / water; N,N-dimethyl-formamide / 12 h / 80 °C / Inert atmosphere

3: 6,7,9,10,12,13,20,21-octahydrodibenzo[b,h][1,4,7,10,13,16]hexaoxacyclooctadecine; sodium hydride / tetrahydrofuran; ethanol / 12 h / 60 °C

4: triethylamine; trifluoroacetic acid / isopropyl alcohol / 3 h / 80 °C

With dichlorobis(tri-O-tolylphosphine)palladium; 6,7,9,10,12,13,20,21-octahydrodibenzo[b,h][1,4,7,10,13,16]hexaoxacyclooctadecine; sodium hydride; potassium carbonate; acetic acid; triethylamine; trifluoroacetic acid; zinc; In tetrahydrofuran; ethanol; water; N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1021/jm2011645