Cyclopropylhydrazine

Base Information

• Chemical Name: Cyclopropylhydrazine
• CAS No.: 120550-58-5
• Molecular Formula: C₃H₈N₂
• Molecular Weight: 72.1099
• DSSTox Substance ID: DTXSID40598916
• Nikkaji Number: J3.349.706G
• Wikidata: Q82494729
• Mol file: 120550-58-5.mol

Synonyms:Cyclopropylhydrazine;120550-58-5;Cyclopropyl-hydrazine;Hydrazine,cyclopropyl-;MFCD07786257;Hydrazine, cyclopropyl-;DTXSID40598916;GPSINNCBFURFNQ-UHFFFAOYSA-N;AKOS006352869;SB31706;SY346044;DB-013992;CS-0183349;P19257

Chemical Property of Cyclopropylhydrazine

Chemical Property:

• XLogP3: -0.4
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 72.068748264
• Heavy Atom Count: 5
• Complexity: 31.9

Purity/Quality:

97% ^*data from raw suppliers

Cyclopropyl-hydrazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC1NN

Technology Process of Cyclopropylhydrazine

There total 3 articles about Cyclopropylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tert-butyl N-(tert-butoxycarbonylamino)-N-cyclopropyl-carbamate (1219020-59-3) → cyclopropyl hydrazine (120550-58-5)

Guidance literature:

With hydrogenchloride; In 1,4-dioxane; at 20 ℃; for 24h;

Reference yield:

1,1-dimethylethyl cyclopropyl(nitroso)carbamate (844872-72-6) → cyclopropyl hydrazine (120550-58-5)

Guidance literature:

With hydrogenchloride; zinc; In methanol; at -78 ℃; for 6h;

Reference yield:

N'-cyclopropyl-hydrazinecarboxylic acid tert-butyl ester (848153-29-7) → cyclopropyl hydrazine (120550-58-5)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 20 ℃;

DOI:10.1016/j.bmcl.2019.01.027

upstream raw materials:

1,1-dimethylethyl cyclopropyl(nitroso)carbamate

tert-butyl N-(tert-butoxycarbonylamino)-N-cyclopropyl-carbamate

N'-cyclopropyl-hydrazinecarboxylic acid tert-butyl ester