2-Biphenylmagnesium bromide

Base Information

• Chemical Name: 2-Biphenylmagnesium bromide
• CAS No.: 82214-69-5
• Molecular Formula: C12H9BrMg
• Molecular Weight: 257.412
• Hs Code.: 29319090
• European Community (EC) Number: 620-693-9,693-054-5
• Mol file: 82214-69-5.mol

Synonyms:2-BIPHENYLMAGNESIUM BROMIDE;82214-69-5;magnesium;phenylbenzene;bromide;3315-91-1;MFCD01311477;2-BIPHENYLYLMAGNESIUM BROMIDE 0.5M IN;biphenyl-2-ylmagnesium bromide;SCHEMBL1270896;AKOS015915882;{[1,1'-biphenyl]-2-yl}(bromo)magnesium;2-Biphenylmagnesium bromide, 0.5 M in 2-MeTHF;2-Biphenylmagnesium bromide 0.5 M in Diethyl Ether;2-Biphenylmagnesium bromide, 0.5M in diethyl ether;2-(Biphenyl)magnesium bromide, 0.50 M in 2-MeTHF

Chemical Property of 2-Biphenylmagnesium bromide

Chemical Property:

• Flash Point: -40 °F
• PSA: 0.00000
• Density: 0.800 g/mL at 25 °C(lit.)
• LogP: 3.99940
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 255.97380
• Heavy Atom Count: 14
• Complexity: 235

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Biphenylmagnesium bromide solution 0.5M in diethyl ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+,C,F
• Hazard Codes: F+,C,F
• Statements: 12-19-22-34-67-14-11
• Safety Statements: 9-16-26-29-33-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC=CC=[C-]2.[Mg+2].[Br-]

Technology Process of 2-Biphenylmagnesium bromide

There total 1 articles about 2-Biphenylmagnesium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Bromobiphenyl (2052-07-5) → 2-biphenylmagnesium bromide (82214-69-5)

Guidance literature:

With magnesium; 1,1-dibromomethane; In diethyl ether; at 50 ℃; for 3h; Heating / reflux;

Reference yield: 87.5%

di(tert-butyl)chlorophosphine (13716-10-4) + 2-biphenylmagnesium bromide (82214-69-5) → johnphos (224311-51-7)

Guidance literature:

copper(I) bromide; In tetrahydrofuran; at 30 - 35 ℃; for 4h; Heating / reflux;

Reference yield: 78.0%

4'-iodo-o-quaterphenyl (97388-39-1) + 2-biphenylmagnesium bromide (82214-69-5) → biphenyl (92-52-4,1594-86-1) + 2,2'-diphenylbiphenyl (641-96-3) + 2-phenyl-3'-(2-biphenylyl)-p-terphenyl (97388-44-8)

Guidance literature:

With bis(acetylacetonate)nickel(II); In benzene; 1) 0 deg C, 1h; 2) reflux, 3 h;

upstream raw materials:

2-Bromobiphenyl

Downstream raw materials:

[1,1';2',1'';3'',1''';4''',1'''']Quinquephenyl

hexakis-biphenyl-2-yl distannane

(o-C₆H₅C₆H₄)3SnBr

Biphenylyl-2-phenylborinsaeure-<2-amino-ethylester>