Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl

Base Information

• Chemical Name: Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl
• CAS No.: 944451-24-5
• Molecular Formula: C₆₂H₆₂Cl₂P₂Ru
• Molecular Weight: 1041.1

Synonyms:BINAP)]Cl;oride [RuCL;(p-cymene)((R)-xyL;[(p-cymene)(DM-BINAP)]CL;}(p-cymene)ruthenium(II) chL;oro{(R)-(+)-2,2'-bis[di(3,5-xyL;[RuCl(p-cymene)((R)-xylbinap)]Cl;-binaphthyl}(p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((R)-xylbinap)]C;CHLORO{(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}(P-CYMENE)RUTHENIUM(II) CHLORIDE,[RUCL(P-CYMENE)((R)-XYLBINAP)]C;Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl

Chemical Property of Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl

Chemical Property:

• Melting Point: >100°C
• PSA: 27.18000
• LogP: 8.77000
• Storage Temp.: 2-8°C
• Sensitive.: air sensitive

Purity/Quality:

98%,99%, ^*data from raw suppliers

[RuCl(p-cymene)((R)-xylbinap)]Cl ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Takasago Ligands and Complexes for Asymmetric Reactions

Technology Process of Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl

There total 1 articles about Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + (S)-2,2'-bis-1,1'-binaphthyl (135139-00-3,137219-86-4,145416-77-9) → [RuCl(p-cymene)((S)-xylbinap)]Cl (1345887-44-6,1365247-39-7,942296-45-9,944451-24-5,944451-25-6)

Guidance literature:

In methanol; at 50 ℃; for 2h; Product distribution / selectivity; Inert atmosphere;

Reference yield:

R-DAIPEN (166764-19-8) + [RuCl(p-cymene)((R)-xylbinap)]Cl (1345887-44-6,1365247-39-7,942296-45-9,944451-24-5,944451-25-6) → trans-RuCl2[(R)-xylbinap][(R)-daipen] (220114-01-2,220114-32-9,294638-74-7)

Guidance literature:

In toluene; at 80 ℃; for 2h; Inert atmosphere;

Reference yield:

(2S)-3-methyl-1,1-diphenylbutane-1,2-diamine + [RuCl(p-cymene)((S)-xylbinap)]Cl (1345887-44-6,1365247-39-7,942296-45-9,944451-24-5,944451-25-6) → RuCl[(S)-xylbinap][(S)-dpipen]

Guidance literature:

With diethylamine; at 50 ℃; for 20h; Inert atmosphere;

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

(S)-2,2'-bis-1,1'-binaphthyl

Downstream raw materials:

trans-RuCl₂[(R)-xylbinap][(R)-daipen]

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