[(1S,2S)-2-Amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1,3,5-trimethylbenzene

Base Information

• Chemical Name: [(1S,2S)-2-Amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1,3,5-trimethylbenzene
• CAS No.: 174813-81-1
• Molecular Formula: C₃₀H₃₃ClN₂O₂RuS
• Molecular Weight: 622.193
• European Community (EC) Number: 692-000-8
• Mol file: 174813-81-1.mol

Synonyms:174813-81-1;RuCl[(S,S)-TsDPEN](mesitylene);[(1S,2S)-2-Amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1,3,5-trimethylbenzene;Ruthenium, [N-[(1S,2S)-2-(amino-kappaN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kappaN]chloro[(1,2,3,4,5,6-eta)-1,3,5-trimethylbenzene]-;J-011043

Chemical Property of [(1S,2S)-2-Amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1,3,5-trimethylbenzene

Chemical Property:

• Melting Point: 241-249°C
• PSA: 66.91000
• LogP: 8.67250
• Storage Temp.: 2-8°C
• Sensitive.: air sensitive
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 622.099467
• Heavy Atom Count: 37
• Complexity: 568

Purity/Quality:

98%,99%, ^*data from raw suppliers

[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)S(=O)(=O)[N-]C(C2=CC=CC=C2)C(C3=CC=CC=C3)N.CC1=CC(=CC(=C1)C)C.Cl[Ru+]
• Isomeric SMILES: CC1=CC=C(C=C1)S(=O)(=O)[N-][C@@H](C2=CC=CC=C2)[C@H](C3=CC=CC=C3)N.CC1=CC(=CC(=C1)C)C.Cl[Ru+]
• Uses: Takasago Ligands and Complexes for Asymmetric Reactions

Technology Process of [(1S,2S)-2-Amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1,3,5-trimethylbenzene

There total 1 articles about [(1S,2S)-2-Amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1,3,5-trimethylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1S,2S)-N-(p-tolylsulfonyl)-1,2-diphenylethylenediamine + {(η6-1,3,5-Me3C6H3)RuCl2}2 → Ru((CH3)3C6H3)Cl(CH3C6H4SO2NCH(C6H5)CH(C6H5)NH2) (388078-96-4,174813-82-2,174813-81-1,388078-97-5)

Guidance literature:

With triethylamine; In isopropyl alcohol; 80°C (1 h);

DOI:10.1021/ja954126l

Reference yield:

Ru((CH3)3C6H3)Cl(CH3C6H4SO2NCH(C6H5)CH(C6H5)NH2) (388078-96-4,174813-82-2,174813-81-1,388078-97-5) → Ru((CH3)3C6H3)Cl(CH3C6H4SO2NCH(C6H5)CH(C6H5)NH2)*3H2O

Guidance literature:

In ethanol; recrystn. of anhydrous Ru complex from ethanol (99%);

DOI:10.1021/ja954126l