Bis(trifluoromethylsulfonyl)azanide;gold(1+);triphenylphosphane

Base Information

• Chemical Name: Bis(trifluoromethylsulfonyl)azanide;gold(1+);triphenylphosphane
• CAS No.: 866395-16-6
• Molecular Formula: C₂₀H₁₅AuF₆NO₄PS₂
• Molecular Weight: 739.406
• Hs Code.: 71159010
• European Community (EC) Number: 812-710-5
• DSSTox Substance ID: DTXSID70475600
• Mol file: 866395-16-6.mol

Synonyms:bis(trifluoromethylsulfonyl)azanide;gold(1+);triphenylphosphane;DTXSID70475600;AMY11806;MFCD12911910;AKOS016009856;FT-0696286;A934911;Gold(1+) bis(trifluoromethanesulfonyl)azanide--triphenylphosphane (1/1/1)

Chemical Property of Bis(trifluoromethylsulfonyl)azanide;gold(1+);triphenylphosphane

Chemical Property:

• PSA: 101.87000
• LogP: 6.05580
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: air sensitive, light sensitive,
• Solubility.: Dichloromethane
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 5
• Exact Mass: 738.975001
• Heavy Atom Count: 35
• Complexity: 575

Purity/Quality:

98%,99%, ^*data from raw suppliers

[Bis(trifluoromethanesulfonyl)imidato](triphenylphosphine)gold(I) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.[Au+]
• Uses: [Bis(trifluoromethanesulfonyl)imidato](triphenylphosphine)gold(I) is a coordination compound.

Technology Process of Bis(trifluoromethylsulfonyl)azanide;gold(1+);triphenylphosphane

There total 9 articles about Bis(trifluoromethylsulfonyl)azanide;gold(1+);triphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + silver(I) triflimide (189114-61-2) → [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (866395-16-6,1246810-76-3)

Guidance literature:

In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1002/anie.201711766

Reference yield: 99.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + silver(I) triflimide (189114-61-2) → [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (866395-16-6,1246810-76-3)

Guidance literature:

In dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere; Darkness;

DOI:10.1021/acs.orglett.1c02360

Reference yield: 90.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + bis(trifluoromethanesulfonyl)amide (82113-65-3) + silver(l) oxide (20667-12-3) → [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (866395-16-6,1246810-76-3)

Guidance literature:

bis(trifluoromethanesulfonyl)amide; silver(l) oxide; In dichloromethane; at 20 ℃; for 12h;

(triphenylphosphine)gold(I) chloride; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1021/acs.orglett.5b01592

upstream raw materials:

[(gold(I))(PPh₃)C(CH₂)CH(CH₂C(COOMe)2CH₂)C₆H₂(OMe)2]

bis(trifluoromethanesulfonyl)amide

[(gold(I))2(PPh₃)2C(CH₂)CH(CH₂C(COOMe)2CH₂)C₆H₂(OMe)2]NTf₂

(triphenylphosphine)gold(I) chloride

Downstream raw materials:

[(gold(I))2(PPh₃)2C(CH₂)CH(CH₂C(COOMe)2CH₂)C₆H₂(OMe)2]NTf₂

[(gold(I))(PPh₃)C(CH₂)CH(CH₂C(COOMe)2CH₂)C₆H₂(OMe)2]

[(Ph₃P)₂Au]⁺SbF₆^-

bromo(triphenylphosphine)gold(I)