Technology Process of (6E,8E)-(6,8-decadien-1-yl) 3,5-dinitrobenzoate and (6Z,8E)-(6,8-decadien-1-yl) 3,5-dinitrobenzoate
There total 1 articles about (6E,8E)-(6,8-decadien-1-yl) 3,5-dinitrobenzoate and (6Z,8E)-(6,8-decadien-1-yl) 3,5-dinitrobenzoate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 95 percent / 10percent aqueous potassium hydroxide / tetrahydrofuran / 0.67 h
2: 1) oxalyl chloride, DMSO, 2) triethylamine / 1) dichloromethane, -60 deg c, 15 min, 2) to room temperature
3: 38 percent / tetrahydrofuran / 1 h / -78 °C
4: 1) n-butyllithium, 1,10-phenanthroline / 1) THF, hexanes, -78 deg C, 5 min, 2) to room temperature, 40 min
5: 8 percent / potassium t-butoxide / tetrahydrofuran / -20 °C
With
potassium hydroxide; n-butyllithium; 1,10-Phenanthroline; oxalyl dichloride; potassium tert-butylate; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran;
DOI:10.1016/S0040-4020(01)96038-7
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 95 percent / 10percent aqueous potassium hydroxide / tetrahydrofuran / 0.67 h
2: 1) oxalyl chloride, DMSO, 2) triethylamine / 1) dichloromethane, -60 deg c, 15 min, 2) to room temperature
3: 38 percent / tetrahydrofuran / 1 h / -78 °C
4: 1) n-butyllithium, 1,10-phenanthroline / 1) THF, hexanes, -78 deg C, 5 min, 2) to room temperature, 40 min
5: 8 percent / potassium t-butoxide / tetrahydrofuran / -20 °C
6: xylene / 312 h / 170 - 178 °C
With
potassium hydroxide; n-butyllithium; 1,10-Phenanthroline; oxalyl dichloride; potassium tert-butylate; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; xylene;
DOI:10.1016/S0040-4020(01)96038-7
