C₃₇H₃₆N₃O₂S⁽¹⁺⁾

Base Information

• Chemical Name: C₃₇H₃₆N₃O₂S⁽¹⁺⁾
• CAS No.: 1333327-07-3
• Molecular Formula: C₃₇H₃₆N₃O₂S
• Molecular Weight: 586.778
• Mol file: 1333327-07-3.mol

Synonyms:

Chemical Property of C₃₇H₃₆N₃O₂S⁽¹⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₇H₃₆N₃O₂S⁽¹⁺⁾

There total 5 articles about C₃₇H₃₆N₃O₂S⁽¹⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

C37H37N3OS (1333327-06-2) → C37H36N3O2S(1+) (1333327-07-3)

Guidance literature:

With chloroauric acid; In ethanol; water; at 20 ℃;

DOI:10.1002/chem.201003586

Reference yield:

rhodamine B (1118784-85-2,14899-08-2) → C37H36N3O2S(1+) (1333327-07-3)

Guidance literature:

Multi-step reaction with 5 steps

1: trichlorophosphate / 1,2-dichloro-ethane / 12 h / Reflux

2: triethylamine / dichloromethane / 25 °C / Inert atmosphere

3: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 16 h / Inert atmosphere

4: Lawessons reagent / benzene / 0.75 h / Inert atmosphere; Reflux

5: chloroauric acid / ethanol; water / 20 °C

With Lawessons reagent; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; chloroauric acid; triethylamine; N-ethyl-N,N-diisopropylamine; trichlorophosphate; In tetrahydrofuran; ethanol; dichloromethane; water; 1,2-dichloro-ethane; benzene;

DOI:10.1002/chem.201003586

Reference yield:

N-(9-(2-(chlorocarbonyl)phenyl)-6-(diethylamino)-3H-xanthen-3-ylidene)-N-ethylethanaminium (770686-36-7) → C37H36N3O2S(1+) (1333327-07-3)

Guidance literature:

Multi-step reaction with 4 steps

1: triethylamine / dichloromethane / 25 °C / Inert atmosphere

2: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 16 h / Inert atmosphere

3: Lawessons reagent / benzene / 0.75 h / Inert atmosphere; Reflux

4: chloroauric acid / ethanol; water / 20 °C

With Lawessons reagent; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; chloroauric acid; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; ethanol; dichloromethane; water; benzene;

DOI:10.1002/chem.201003586

upstream raw materials:

N-(9-(2-(chlorocarbonyl)phenyl)-6-(diethylamino)-3H-xanthen-3-ylidene)-N-ethylethanaminium

3',6'-bis(diethylamino)-2-(prop-2-yn-1-yl)spiro[isoindoline-1,9'-xanthen]-3-one

C₃₇H₃₇N₃O₂

C₃₇H₃₇N₃OS

Refernces