bromo(tetracarbonyl)-[(3-chloropropyl)diphenylarsane]manganese

Base Information

• Chemical Name: bromo(tetracarbonyl)-[(3-chloropropyl)diphenylarsane]manganese
• CAS No.: 84630-78-4
• Molecular Formula: C₁₉H₁₆AsBrClMnO₄
• Molecular Weight: 553.55
• Mol file: 84630-78-4.mol

Synonyms:

Chemical Property of bromo(tetracarbonyl)-[(3-chloropropyl)diphenylarsane]manganese

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bromo(tetracarbonyl)-[(3-chloropropyl)diphenylarsane]manganese

There total 1 articles about bromo(tetracarbonyl)-[(3-chloropropyl)diphenylarsane]manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.5%

bromopentacarbonylmanganese(I) (14516-54-2) + (3-chloropropyl)diphenylarsine (59579-06-5) → bromo(tetracarbonyl)-[(3-chloropropyl)diphenylarsane]manganese (84630-78-4)

Guidance literature:

In hexane; byproducts: CO; under N2; 70°C; 1 h after complete reaction; cooled to room temperature; filtered; solvent was removed in vacuo; warm hexane was added; crystallized at -30.degree; IR, elem. anal.;

Reference yield: 58.2%

bromo(tetracarbonyl)-[(3-chloropropyl)diphenylarsane]manganese (84630-78-4) → 2.2.2.2-tetracarbonyl-1.1-diphenyl-1-arsa-2-manganacyclopentane

Guidance literature:

With Na/Hg; In tetrahydrofuran; byproducts: NaCl, NaBr; under N2; to a 30-40% excess of 1%-Na/Hg was added the MnAs-compound atroom temperature; 3 h; solvent was removed in vacuo; extracted 3 times with hexane; solvent was removed in vacuo; chromatographed; elem. anal.;

Reference yield:

bromo(tetracarbonyl)-[(3-chloropropyl)diphenylarsane]manganese (84630-78-4) → 2.2.2.2-tetracarbonyl-3.3-diphenyl-1-thia-3-arsa-2-manganacyclohexan-S.S-dioxide

Guidance literature:

Multi-step reaction with 2 steps

1: Na/Hg / tetrahydrofuran

2: SO₂ / sulfur dioxide

With Na/Hg; SO₂; In tetrahydrofuran; sulfur dioxide;

upstream raw materials:

bromopentacarbonylmanganese(I)

(3-chloropropyl)diphenylarsine