Trimethyl[(3-methylphenyl)ethynyl]silane

Base Information

Chemical Name:Trimethyl[(3-methylphenyl)ethynyl]silane
CAS No.:40230-90-8
Molecular Formula:C12H16Si
Molecular Weight:188.345
Hs Code.:2931900090
DSSTox Substance ID:DTXSID50701217
Nikkaji Number:J559.024H
Wikidata:Q72495478
Mol file:40230-90-8.mol

Synonyms:40230-90-8;trimethyl[(3-methylphenyl)ethynyl]silane;Trimethyl-m-tolylethynyl-silane;3-[(Trimethylsilyl)ethynyl]toluene;A6730;trimethyl-[2-(3-methylphenyl)ethynyl]silane;Trimethyl(m-tolylethynyl)silane;DTXSID50701217;trimethyl(2-m-tolylethynyl)silane;MFCD18207391;Trimethyl(3-methylphenylethynyl)silane

Suppliers and Price of Trimethyl[(3-methylphenyl)ethynyl]silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Rieke Metals
Trimethyl-m-tolylethynyl-silane
1g
$ 661.00

Total 18 raw suppliers

Chemical Property of Trimethyl[(3-methylphenyl)ethynyl]silane

Chemical Property:

Boiling Point:230℃
Flash Point:88℃
PSA：0.00000
Density:0.90
LogP:3.22390
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:188.102127045
Heavy Atom Count:13
Complexity:223

Purity/Quality:

97% ^*data from raw suppliers

Trimethyl-m-tolylethynyl-silane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=CC=C1)C#C[Si](C)(C)C

Technology Process of Trimethyl[(3-methylphenyl)ethynyl]silane

There total 5 articles about Trimethyl[(3-methylphenyl)ethynyl]silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 625-95-6
3-Iodotoluene

: 1066-54-2
trimethylsilylacetylene

: 40230-90-8
(2-(3-methylphenyl)ethynyl)trimethylsilane

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; at 25 ℃; for 0.5h; Inert atmosphere;
DOI:10.1002/chem.201405903

Reference yield: 91.1%

: 591-17-3
meta-bromotoluene

: 1066-54-2
trimethylsilylacetylene

: 40230-90-8
(2-(3-methylphenyl)ethynyl)trimethylsilane

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In acetonitrile; at 120 ℃; for 0.0833333h; Microwave irradiation; Sealed tube; Inert atmosphere;
DOI:10.1016/j.tetlet.2016.01.088

Reference yield: 83.0%

: 625-95-6
3-Iodotoluene

: 250643-77-7
tris(2-(trimethylsilyl)ethynyl)indium

: 40230-90-8
(2-(3-methylphenyl)ethynyl)trimethylsilane

Guidance literature:: With 3-aminopropyl-functionalized silica supported MCM-41-immobilized palladium⁽⁰⁾-[(pyridin-2-yl)methylidene]amine complex; In tetrahydrofuran; at 68 ℃; for 2h; Inert atmosphere;
DOI:10.1016/j.jorganchem.2017.10.013