(S)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

Base Information

Chemical Name:(S)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde
CAS No.:51619-87-5
Molecular Formula:C₁₅H₂₄O₂
Molecular Weight:236.354
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

Chemical Property:

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Technology Process of (S)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

There total 11 articles about (S)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 262290-99-3
(1S)-5-[(1S)-3-Hydroxy-1,5-dimethylhexyl]-2-methylenecyclohexanol

: 51619-87-5
(S)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

Guidance literature:: With toluene-4-sulfonic acid; pyridinium chlorochromate; In dichloromethane; for 3h;

Reference yield:

: 5989-54-8,555-08-8,8022-90-0,9003-73-0,95327-98-3
(-)-(S)-limonene

: 51619-87-5
(S)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

Guidance literature:: Multi-step reaction with 8 steps

1.1: n-BuLi; TMEDA / hexane / 20 °C

1.2: hexane / -78 - 0 °C

2.1: activity grade I alumina / diethyl ether / 2 h

3.1: baker's yeast; resin XAD; glucose / H₂O / 96 h / 20 °C / Microbiological reaction

4.1: 94 percent / PCC / CH₂Cl₂ / 1 h / 20 °C

5.1: 76 percent / tetrahydrofuran / 1 h / 0 °C

6.1: MCPBA / CH₂Cl₂ / 1 h / 0 °C

7.1: LDA / tetrahydrofuran / 2 h / Heating

8.1: PCC; TsOH / CH₂Cl₂ / 3 h

With aluminum oxide; n-butyllithium; baker's yeast; D-glucose; N,N,N,N,-tetramethylethylenediamine; resin XAD; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; water; 1.1: Metallation / 1.2: Formylation / 2.1: Isomerization / 3.1: Reduction / 4.1: Oxidation / 5.1: Grignard reaction / 6.1: Epoxidation / 7.1: Isomerization / 8.1: Isomerization;

Reference yield:

: 156406-00-7
(E)-3-([1S)-4-Methylcyclohex-3-enyl]but-2-enal

: 51619-87-5
(S)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

Guidance literature:: Multi-step reaction with 6 steps

1: baker's yeast; resin XAD; glucose / H₂O / 96 h / 20 °C / Microbiological reaction

2: 94 percent / PCC / CH₂Cl₂ / 1 h / 20 °C

3: 76 percent / tetrahydrofuran / 1 h / 0 °C

4: MCPBA / CH₂Cl₂ / 1 h / 0 °C

5: LDA / tetrahydrofuran / 2 h / Heating

6: PCC; TsOH / CH₂Cl₂ / 3 h

With baker's yeast; D-glucose; resin XAD; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; water; 1: Reduction / 2: Oxidation / 3: Grignard reaction / 4: Epoxidation / 5: Isomerization / 6: Isomerization;