Cp₂Ti[2,6-dimethylphenoxide]

Base Information

• Chemical Name: Cp₂Ti[2,6-dimethylphenoxide]
• CAS No.: 845963-02-2
• Molecular Formula: C₁₈H₁₉OTi
• Molecular Weight: 299.228
• Mol file: 845963-02-2.mol

Synonyms:

Chemical Property of Cp₂Ti[2,6-dimethylphenoxide]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Cp₂Ti[2,6-dimethylphenoxide]

There total 1 articles about Cp₂Ti[2,6-dimethylphenoxide] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

bis(cyclopentadienyl)-titanium(III) chloride + lithium 2,6-dimethylphenolate dimer (24560-29-0) → Cp2Ti[2,6-dimethylphenoxide] (845963-02-2)

Guidance literature:

In tetrahydrofuran; (N2): stirring a mixt. of titanium complex with lithium salt in THF overnight at room temp.; concn., extn. with toluene, evapn., sublimation (2E-2 Torr, 90°C), recrystn. (THF/pentane); elem. anal.;

DOI:10.1016/j.jorganchem.2004.09.075

Reference yield: 40.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + Cp2Ti[2,6-dimethylphenoxide] (845963-02-2) → Cp2Ti(2,6-dimethylphenolato)(μ-CO)(CO)Co3(CO)9

Guidance literature:

In toluene; (N2): dissolving titanium and cobalt complexes in toluene, stirring for 2 d at room temp.; evapn., sublimation of Co2(CO)8 (1E-3 Torr, room temp, 1 d), recrystn. (toluene, -35°C); elem. anal.;

DOI:10.1016/j.jorganchem.2004.09.075

Reference yield:

bis(tricarbonyl(η-cyclopentadienyl)tungsten) + Cp2Ti[2,6-dimethylphenoxide] (845963-02-2) → Cp2Ti(2,6-dimethylphenolato)(μ-CO)(CO)2WCp

Guidance literature:

In ⁽²⁾H₈-toluene; (N2): dissolving titanium and tungsten complexes in toluene-d8 in an NMRtube; not isolated, detected by NMR;

DOI:10.1016/j.jorganchem.2004.09.075

upstream raw materials:

lithium 2,6-dimethylphenolate dimer