(Z)-1-allyloxy-4-(prop-1-en-1-yl)benzene

Base Information

Chemical Name:(Z)-1-allyloxy-4-(prop-1-en-1-yl)benzene
CAS No.:1369494-79-0
Molecular Formula:C₁₂H₁₄O
Molecular Weight:174.243
Hs Code.:

Synonyms:

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Chemical Property of (Z)-1-allyloxy-4-(prop-1-en-1-yl)benzene

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Technology Process of (Z)-1-allyloxy-4-(prop-1-en-1-yl)benzene

There total 5 articles about (Z)-1-allyloxy-4-(prop-1-en-1-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 40663-68-1
4-(2-propenyloxy)benzaldehyde

: 2065-66-9
methyl-triphenylphosphonium iodide

: 1369494-79-0
(Z)-1-allyloxy-4-(prop-1-en-1-yl)benzene

: 305815-25-2
(E)-1-(allyloxy)-4-(prop-1-en-1-yl)benzene

Guidance literature:: methyl-triphenylphosphonium iodide; With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 1h; Inert atmosphere;

4-(2-propenyloxy)benzaldehyde; In tetrahydrofuran; hexane; at 20 ℃; for 2h; Overall yield = 99 %;
DOI:10.1021/acs.orglett.8b02541

Reference yield:

: 40663-68-1
4-(2-propenyloxy)benzaldehyde

: 1530-32-1
ethyltriphenylphosphonium bromide

: 1369494-79-0
(Z)-1-allyloxy-4-(prop-1-en-1-yl)benzene

: 305815-25-2
(E)-1-(allyloxy)-4-(prop-1-en-1-yl)benzene

Guidance literature:: ethyltriphenylphosphonium bromide; With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;

4-(2-propenyloxy)benzaldehyde; In tetrahydrofuran; at -78 - 20 ℃; for 15h; optical yield given as %de; Inert atmosphere;
DOI:10.1039/c2cc17572j

Reference yield:

: 106-41-2
4-bromo-phenol

: 1369494-79-0
(Z)-1-allyloxy-4-(prop-1-en-1-yl)benzene

Guidance literature:: Multi-step reaction with 4 steps

1.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / 1,2-dimethoxyethane; water / 20 h / Inert atmosphere; Reflux

2.1: potassium carbonate / acetone / 4 h / 20 °C / Reflux

3.1: oxygen / dimethyl sulfoxide / 24 h / 20 °C / 1500.15 Torr / pH 6 / aq. buffer; Enzymatic reaction

4.1: potassium tert-butylate / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere

4.2: 15 h / -78 - 20 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium tert-butylate; oxygen; sodium carbonate; potassium carbonate; In tetrahydrofuran; 1,2-dimethoxyethane; water; dimethyl sulfoxide; acetone; 1.1: Suzuki-Miyaura cross-coupling / 4.2: Wittig reaction;
DOI:10.1039/c2cc17572j