dicarbonylcyclopentadienyl(4-(hydroxydiphenylmethyl)phenyl)iron

Base Information

• Chemical Name: dicarbonylcyclopentadienyl(4-(hydroxydiphenylmethyl)phenyl)iron
• CAS No.: 1184303-75-0
• Molecular Formula: C₂₆H₂₀FeO₃
• Molecular Weight: 436.29
• Mol file: 1184303-75-0.mol

Synonyms:

Chemical Property of dicarbonylcyclopentadienyl(4-(hydroxydiphenylmethyl)phenyl)iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonylcyclopentadienyl(4-(hydroxydiphenylmethyl)phenyl)iron

There total 1 articles about dicarbonylcyclopentadienyl(4-(hydroxydiphenylmethyl)phenyl)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

[CpFe(CO)2C6H4-4-C(O)OEt] (1083330-11-3) + phenyllithium (591-51-5) → dicarbonylcyclopentadienyl(4-(hydroxydiphenylmethyl)phenyl)iron (1184303-75-0)

Guidance literature:

In tetrahydrofuran; diethyl ether; cyclohexane; soln. of PhLi (2.5 equiv.) in cyclohexane/Et2O was added to soln. of Fe complex in THF at -20°C under Ar; stirred at -20°C for 1 h; satd. soln. of NH4Cl added; filtered through silica gel; concd.; chromd.(silica gel, hexane/EtOAc, 40/1); elem. anal.;

DOI:10.1021/om900558a

upstream raw materials:

[CpFe(CO)2C₆H₄-4-C(O)OEt]

phenyllithium