{Pd(II)Cl₂(diphenylvinylphosphine)2}

Base Information

• Chemical Name: {Pd(II)Cl₂(diphenylvinylphosphine)2}
• CAS No.: 113214-83-8
• Molecular Formula: C₂₈H₂₆Cl₂P₂Pd
• Molecular Weight: 601.788
• Mol file: 113214-83-8.mol

Synonyms:

Chemical Property of {Pd(II)Cl₂(diphenylvinylphosphine)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Pd(II)Cl₂(diphenylvinylphosphine)2}

There total 6 articles about {Pd(II)Cl₂(diphenylvinylphosphine)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.9%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + Diphenylvinylphosphine (2155-96-6) → cis-dichlorobis(diphenylvinylphosphine)palladium(II) (113214-83-8)

Guidance literature:

In dichloromethane; To a soln. of dichlorobis(benzonitrile)palladium(II) in CH2Cl2 under N2 was added diphenylvinylphosphine via syringe. The resulting soln. was stirred for 4 h at ambient temp.; The soln. was filtered and the solvent reduced in vol. Methanol was added to induce crystn., and the plates that resulted were isolated by filtration, washed with cold methanol, and vac.-dried overnight. Elem.anal.;

Reference yield: 84.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + Diphenylvinylphosphine (2155-96-6) → {Pd(II)Cl2(diphenylvinylphosphine)2} (78629-73-9,113214-83-8,98717-39-6)

Guidance literature:

In benzene; (N2); addn. of phosphine to a stirred soln. of Pd-complex; mixture of cis/trans isomers; filtration after 1 h; cooling to ca. 5°C; crystn.; collection; drying; elem. anal.; (1)H-NMR; (31)P-NMR;

DOI:10.1016/0022-328X(90)80161-R

Reference yield:

C26H26Cl2P2Pd (98651-92-4) + cis-(1-phenyl-3,4-dimethylphosphole)(Ph2VyP)palladium(II)Cl2 (122109-36-8) → (1-phenyl-3,4-dimethylphosphole)2PdCl2 (72937-30-5,66368-11-4,73244-96-9) + {Pd(II)Cl2(diphenylvinylphosphine)2} (78629-73-9,113214-83-8,98717-39-6)

Guidance literature:

In chloroform-d1; equilibrium, NMR-tube, 300 K; not isolated; (31)P-NMR-monitoring;

DOI:10.1016/S0277-5387(00)86441-4

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

Diphenylvinylphosphine

ethyl-diphenyl-phosphane

borane-THF

Downstream raw materials:

trans-diiodobis(diphenylvinylphosphine)palladium(II)

trans-dichlorobis(diphenylvinylphosphine)palladium(II)

sym-[(PdCl₂(diphenyl-vinylphosphine))2]

sym-[(PdCl₂(Ph₂CH₂CH₂BH₂))2]

Refernces

• 1、 Fontaine, Xavier L. R.,Markham, David P.,Shaw, Bernard, L.. "Complexes of Ph2PCH=CH2 with PtX2 (X = Cl, Br, I or Me) or PdX2 (X = Cl, Br or I)". . p. 123 - 129. Retrieved 2007/10/02.