Technology Process of 2-(4,5-hexadienyl)-2-cyclohexen-1-one
There total 6 articles about 2-(4,5-hexadienyl)-2-cyclohexen-1-one which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tetraethylammonium tosylate;
In
acetic acid;
for 30h;
electrochemical oxidation;
DOI:10.1021/jo00138a019
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 100 percent / triethylamine / tetrahydrofuran / 2 h / 0 °C
2: 87 percent / NaI / tetrahydrofuran / Ambient temperature
3: 1.) n-butyllithium / 1.) THF, hexane, -78 deg C, 0.5 h, 2.) HMPA, 0.5 h
4: 100 percent / ethanol, H2O, 32percent HCl / CH2Cl2 / Ambient temperature
5: 51 percent / 70percent aq. perchloric acid / CCl4
6: 26 percent / tetraethylammonium tosylate / acetic acid / 30 h / electrochemical oxidation
With
hydrogenchloride; n-butyllithium; perchloric acid; ethanol; water; tetraethylammonium tosylate; triethylamine; sodium iodide;
In
tetrahydrofuran; tetrachloromethane; dichloromethane; acetic acid;
DOI:10.1021/jo00138a019
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) n-butyllithium / 1.) THF, hexane, -78 deg C, 0.5 h, 2.) HMPA, 0.5 h
2: 100 percent / ethanol, H2O, 32percent HCl / CH2Cl2 / Ambient temperature
3: 51 percent / 70percent aq. perchloric acid / CCl4
4: 26 percent / tetraethylammonium tosylate / acetic acid / 30 h / electrochemical oxidation
With
hydrogenchloride; n-butyllithium; perchloric acid; ethanol; water; tetraethylammonium tosylate;
In
tetrachloromethane; dichloromethane; acetic acid;
DOI:10.1021/jo00138a019
