C₇₃H₁₀₄O₉Si₃

Base Information

Chemical Name:C₇₃H₁₀₄O₉Si₃
CAS No.:1261152-31-1
Molecular Formula:C₇₃H₁₀₄O₉Si₃
Molecular Weight:1209.88
Hs Code.:

C<sub>73</sub>H<sub>104</sub>O<sub>9</sub>Si<sub>3</sub>

Synonyms:

Suppliers and Price of C₇₃H₁₀₄O₉Si₃

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₇₃H₁₀₄O₉Si₃

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₇₃H₁₀₄O₉Si₃

There total 31 articles about C₇₃H₁₀₄O₉Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 557-91-5
1,1-Dibromoethane

: 1261152-50-4
C₇₁H₁₀₀O₁₀Si₃

: 1261152-32-2
C₆₉H₉₆O₉Si₃

: 1261152-31-1
C₇₃H₁₀₄O₉Si₃

Guidance literature:: With N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; In tetrahydrofuran; dichloromethane; at 0 - 25 ℃; Inert atmosphere;

With lead(II) chloride; zinc; In tetrahydrofuran; dichloromethane; at 25 ℃; for 0.666667h; Inert atmosphere;

1,1-Dibromoethane; C₇₁H₁₀₀O₁₀Si₃; Further stages;
DOI:10.1021/ja109533y

Reference yield:

: C₃₁H₅₀O₅Si₂

: 1261152-31-1
C₇₃H₁₀₄O₉Si₃

Guidance literature:: Multi-step reaction with 18 steps

1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.17 h / -78 °C / Inert atmosphere

1.2: 1 h / -78 °C / Inert atmosphere

1.3: 2 h / -78 - 0 °C / Inert atmosphere

2.1: dichloromethane / 1.5 h / 25 °C / Inert atmosphere

3.1: 2,6-dimethylpyridine / dichloromethane / 14 h / 0 °C / Inert atmosphere

4.1: diisobutylaluminium hydride / dichloromethane / 1 h / -78 °C / Inert atmosphere

4.2: 16 h / 25 °C / Inert atmosphere

5.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 1 h / -25 °C / Inert atmosphere; Molecular sieve

5.2: 17 h / -20 °C / Inert atmosphere; Molecular sieve

6.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

7.1: dichloromethane / 14 h / 20 °C / Inert atmosphere

8.1: tetrabutyl ammonium fluoride / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

9.1: pyridinium p-toluenesulfonate / dichloromethane / 25 - 40 °C / Inert atmosphere

10.1: lanthanum(lll) triflate / toluene / 6 h / 25 °C / Inert atmosphere

11.1: sodium tetrahydroborate; nickel (II) chloride hexahydrate / ethanol / 0 °C / Inert atmosphere

12.1: lithium aluminium tetrahydride / tetrahydrofuran; diethyl ether / 0.5 h / 25 °C / Inert atmosphere

13.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

14.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 °C / Inert atmosphere

14.2: 0.33 h / 0 °C / Inert atmosphere

15.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 3 h / 0 °C / Inert atmosphere

16.1: dmap; 2-methyl-6-nitrobenzoic anhydride; triethylamine / toluene / 0.33 h / 25 °C / Inert atmosphere; Molecular sieve

16.2: 13 h / 25 °C / Inert atmosphere; Molecular sieve

17.1: p-toluenesulfonic acid monohydrate / methanol; dichloromethane / 0.67 h / 0 °C / Inert atmosphere

18.1: N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride / tetrahydrofuran; dichloromethane / 0 - 25 °C / Inert atmosphere

18.2: 0.67 h / 25 °C / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; dmap; sodium tetrahydroborate; lithium aluminium tetrahydride; oxalyl dichloride; nickel (II) chloride hexahydrate; diethyl (2S,3S)-tartrate; N,N,N,N,-tetramethylethylenediamine; 2-methyl-6-nitrobenzoic anhydride; p-toluenesulfonic acid monohydrate; tetrabutyl ammonium fluoride; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; titanium tetrachloride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lanthanum(lll) triflate; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; toluene; 1.1: Swern oxidation / 1.2: Swern oxidation / 1.3: Swern oxidation / 2.1: Wittig reaction / 5.1: Sharpless epoxidation / 5.2: Sharpless epoxidation / 6.1: Parikh-Doering oxidation / 7.1: Wittig reaction / 13.1: Parikh-Doering oxidation / 14.1: Wittig reaction / 14.2: Wittig reaction;
DOI:10.1021/ja109533y

Reference yield:

: C₃₉H₆₄O₆Si₃

: 1261152-31-1
C₇₃H₁₀₄O₉Si₃

Guidance literature:: Multi-step reaction with 15 steps

1.1: diisobutylaluminium hydride / dichloromethane / 1 h / -78 °C / Inert atmosphere

1.2: 16 h / 25 °C / Inert atmosphere

2.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 1 h / -25 °C / Inert atmosphere; Molecular sieve

2.2: 17 h / -20 °C / Inert atmosphere; Molecular sieve

3.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

4.1: dichloromethane / 14 h / 20 °C / Inert atmosphere

5.1: tetrabutyl ammonium fluoride / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

6.1: pyridinium p-toluenesulfonate / dichloromethane / 25 - 40 °C / Inert atmosphere

7.1: lanthanum(lll) triflate / toluene / 6 h / 25 °C / Inert atmosphere

8.1: sodium tetrahydroborate; nickel (II) chloride hexahydrate / ethanol / 0 °C / Inert atmosphere

9.1: lithium aluminium tetrahydride / tetrahydrofuran; diethyl ether / 0.5 h / 25 °C / Inert atmosphere

10.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

11.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 °C / Inert atmosphere

11.2: 0.33 h / 0 °C / Inert atmosphere

12.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 3 h / 0 °C / Inert atmosphere

13.1: dmap; 2-methyl-6-nitrobenzoic anhydride; triethylamine / toluene / 0.33 h / 25 °C / Inert atmosphere; Molecular sieve

13.2: 13 h / 25 °C / Inert atmosphere; Molecular sieve

14.1: p-toluenesulfonic acid monohydrate / methanol; dichloromethane / 0.67 h / 0 °C / Inert atmosphere

15.1: N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride / tetrahydrofuran; dichloromethane / 0 - 25 °C / Inert atmosphere

15.2: 0.67 h / 25 °C / Inert atmosphere

With titanium(IV) isopropylate; dmap; sodium tetrahydroborate; lithium aluminium tetrahydride; nickel (II) chloride hexahydrate; diethyl (2S,3S)-tartrate; N,N,N,N,-tetramethylethylenediamine; 2-methyl-6-nitrobenzoic anhydride; p-toluenesulfonic acid monohydrate; tetrabutyl ammonium fluoride; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; titanium tetrachloride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lanthanum(lll) triflate; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; toluene; 2.1: Sharpless epoxidation / 2.2: Sharpless epoxidation / 3.1: Parikh-Doering oxidation / 4.1: Wittig reaction / 10.1: Parikh-Doering oxidation / 11.1: Wittig reaction / 11.2: Wittig reaction;
DOI:10.1021/ja109533y