2,2a,7,7a-tetrahydro-2a-methyl-7-phenyl-2,7-methano-1H-cyclobutindene

Base Information

• Chemical Name: 2,2a,7,7a-tetrahydro-2a-methyl-7-phenyl-2,7-methano-1H-cyclobut
• Molecular Formula: C₁₉H₁₈
• Molecular Weight: 246.352

Synonyms:

Chemical Property of 2,2a,7,7a-tetrahydro-2a-methyl-7-phenyl-2,7-methano-1H-cyclobut

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

There total 2 articles about 2,2a,7,7a-tetrahydro-2a-methyl-7-phenyl-2,7-methano-1H-cyclobutindene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

1-allyl-3-methyl-1-phenylindene (74534-18-2) → 1-methyl-2-phenyl-3-allylindene (62907-53-3) + 1-allyl-2-phenyl-3-methylindene (74534-20-6) + 2,2a,7,7a-tetrahydro-2a-methyl-7-phenyl-2,7-methano-1H-cyclobutindene (74534-19-3)

Guidance literature:

With thio-xanthene-9-one; In benzene; for 9h; Irradiation;

DOI:10.1021/jo00141a018

Reference yield: 32.0%

1-allyl-3-methyl-1-phenylindene (74534-18-2) → 1-methyl-2-phenyl-3-allylindene (62907-53-3) + 1-allyl-2-phenyl-3-methylindene (74534-20-6) + 2,2a,7,7a-tetrahydro-2a-methyl-7-phenyl-2,7-methano-1H-cyclobutindene (74534-19-3)

Guidance literature:

Irradiation; thioxanthone;

DOI:10.1021/ja00540a056

Reference yield:

2,2a,7,7a-tetrahydro-2a-methyl-7-phenyl-2,7-methano-1H-cyclobutindene (74534-19-3) → 1-allyl-1-methyl-3-phenylindene (74534-16-0)

Guidance literature:

at 160 ℃;

DOI:10.1021/ja00540a056

upstream raw materials:

1-allyl-3-methyl-1-phenylindene

Downstream raw materials:

1-allyl-1-methyl-3-phenylindene

1-allyl-3-methyl-1-phenylindene

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