triiodo(tetrahydrofuran)3molybdenum

Base Information

• Chemical Name: triiodo(tetrahydrofuran)3molybdenum
• CAS No.: 165522-00-9
• Molecular Formula: C₁₂H₂₄I₃MoO₃
• Molecular Weight: 692.974
• Mol file: 165522-00-9.mol

Synonyms:

Chemical Property of triiodo(tetrahydrofuran)3molybdenum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triiodo(tetrahydrofuran)3molybdenum

There total 1 articles about triiodo(tetrahydrofuran)3molybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

MoI2(CO)3(THF)2 (103904-36-5) → triiodo(tetrahydrofuran)3molybdenum (165522-00-9,107680-52-4) + molybdenum hexacarbonyl (13939-06-5,199620-15-0)

Guidance literature:

In tetrahydrofuran; byproducts: carbon monoxide; disproportionation reaction at room temp. accelerated at reflux temp.;

DOI:10.1021/ja00211a023

Reference yield: 88.0%

triiodo(tetrahydrofuran)3molybdenum (165522-00-9,107680-52-4) + cyclopentadienylthallium(I) → cyclopentadienylmolybdenum(III)(bis(diphenylphosphino)ethane)I2

Guidance literature:

With C₂H₄(P(C₆H₅)2)2; In tetrahydrofuran; byproducts: TlI; react. of Mo-compd. with dppe, addn. of TlCp and stirring at room temp. (under N2, Schlenk app.); monitored by ESR, filtn., pptn. from filtrate with heptane, diffusion of heptane in CH2Cl2 soln. gives crystals, elem. anal.;

Reference yield: 83.0%

triiodo(tetrahydrofuran)3molybdenum (165522-00-9,107680-52-4) + Dimethyl(phenyl)phosphine (672-66-2) → Mo2I6(P(CH3)2(C6H5))3

Guidance literature:

In toluene; byproducts: THF; under nitrogen, refluxed overnight; filtered, washed (toluene), dried in vacuo; elem. anal.;

DOI:10.1016/S0277-5387(00)83780-8

upstream raw materials:

MoI₂(CO)3(THF)2

Downstream raw materials:

MoI₃(bis(diphenylphosphino) ethane)(MeCN)

mer-MoI₃(bis(diphenylphosphino) ethane)(THF)

{MoI₃(((C₆H₅)2PCH₂)2)}

cis-[Na(tetrahydrofuran)3][MoI₄(dppe)]