(Z)-1-(tri-n-butylstannyl)-1-methoxy-2-phenylethene

Base Information

• Chemical Name: (Z)-1-(tri-n-butylstannyl)-1-methoxy-2-phenylethene
• CAS No.: 340016-58-2
• Molecular Formula: C₂₁H₃₆OSn
• Molecular Weight: 423.226
• Mol file: 340016-58-2.mol

Synonyms:

Chemical Property of (Z)-1-(tri-n-butylstannyl)-1-methoxy-2-phenylethene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-1-(tri-n-butylstannyl)-1-methoxy-2-phenylethene

There total 1 articles about (Z)-1-(tri-n-butylstannyl)-1-methoxy-2-phenylethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tributyltin chloride (1461-22-9) + phenylacetaldehyde dimethyl acetal (101-48-4) → (Z)-1-(tri-n-butylstannyl)-1-methoxy-2-phenylethene (340016-58-2)

Guidance literature:

With n-butyllithium; potassium tert-butylate; In tetrahydrofuran; hexane; under Ar; acetal and soln. of BuLi in hexane added dropwise to cooled (-95°C) soln. of t-BuOK in anhyd. THF (molar ratio 1:2.5:2.5); stirred for 2 h at -95°C; 1 equiv. of ClSnBu3 added; 2 h; quenched with THF soln. of H2O; two phases sepd.; aq. phase extd. with Et2O; combined org. phases washedwith brine; dried (Na2SO4); concd.; purified by column chromy. (silica gel, Et2O-light petroleum ether - 2:98); elem. anal.;

DOI:10.1039/b007500k

upstream raw materials:

tributyltin chloride

phenylacetaldehyde dimethyl acetal