(5R)-1-(4-Benzyloxy-3-methoxyphenyl)-5-hydroxy-4-(4-methylphenylsulfinyl)-3-decanone dimethylhydrazone

Base Information

Chemical Name:(5R)-1-(4-Benzyloxy-3-methoxyphenyl)-5-hydroxy-4-(4-methylphenylsulfinyl)-3-decanone dimethylhydrazone
CAS No.:94272-48-7
Molecular Formula:C₃₃H₄₄N₂O₄S
Molecular Weight:564.789
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (5R)-1-(4-Benzyloxy-3-methoxyphenyl)-5-hydroxy-4-(4-methylphenylsulfinyl)-3-decanone dimethylhydrazone

Chemical Property:

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Technology Process of (5R)-1-(4-Benzyloxy-3-methoxyphenyl)-5-hydroxy-4-(4-methylphenylsulfinyl)-3-decanone dimethylhydrazone

There total 3 articles about (5R)-1-(4-Benzyloxy-3-methoxyphenyl)-5-hydroxy-4-(4-methylphenylsulfinyl)-3-decanone dimethylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 72724-09-5
4-(4-Benzyloxy-3-methoxyphenyl)-2-butanone dimethylhydrazone

: 94272-48-7,94346-27-7
(5R)-1-(4-Benzyloxy-3-methoxyphenyl)-5-hydroxy-4-(4-methylphenylsulfinyl)-3-decanone dimethylhydrazone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) LiN(C₃H₇-i)2 / 1.) THF, hexane, -78 -> 0 deg C, 2 h, 2.) -78 deg C, 40 min.

2: 1.) n-butyllithium, 2.) HMPT / 1.) THF, hexane, -85 deg C, 30 min., 2.) -85 -> -10 deg C, 45 min., 3.) -10 deg C, 1 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; lithium diisopropyl amide;
DOI:10.1055/s-1984-30942

Reference yield:

: 1517-82-4
(1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate

: 94272-48-7,94346-27-7
(5R)-1-(4-Benzyloxy-3-methoxyphenyl)-5-hydroxy-4-(4-methylphenylsulfinyl)-3-decanone dimethylhydrazone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) LiN(C₃H₇-i)2 / 1.) THF, hexane, -78 -> 0 deg C, 2 h, 2.) -78 deg C, 40 min.

2: 1.) n-butyllithium, 2.) HMPT / 1.) THF, hexane, -85 deg C, 30 min., 2.) -85 -> -10 deg C, 45 min., 3.) -10 deg C, 1 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; lithium diisopropyl amide;
DOI:10.1055/s-1984-30942

Reference yield:

: 94272-47-6,94272-51-2
(+)-(R)-4-(4-Benzyloxy-3-methoxyphenyl)-1-(4-methylphenylsulfinyl)-2-butanone dimethylhydrazone

: 66-25-1
hexanal

: 94272-48-7,94346-27-7
(5R)-1-(4-Benzyloxy-3-methoxyphenyl)-5-hydroxy-4-(4-methylphenylsulfinyl)-3-decanone dimethylhydrazone

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; Yield given. Multistep reaction; 1.) THF, hexane, -85 deg C, 30 min., 2.) -85 -> -10 deg C, 45 min., 3.) -10 deg C, 1 h;
DOI:10.1055/s-1984-30942