Triisopropyl-((1S,3S)-4-{(4S,5S)-5-[(1E,5E)-7-(4-methoxy-benzyloxy)-6-methyl-hepta-1,5-dienyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1,3-dimethyl-butoxy)-silane

Base Information

Chemical Name:Triisopropyl-((1S,3S)-4-{(4S,5S)-5-[(1E,5E)-7-(4-methoxy-benzyloxy)-6-methyl-hepta-1,5-dienyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1,3-dimethyl-butoxy)-silane
CAS No.:224623-16-9
Molecular Formula:C₃₆H₆₂O₅Si
Molecular Weight:602.971
Hs Code.:

Triisopropyl-((1S,3S)-4-{(4S,5S)-5-[(1E,5E)-7-(4-methoxy-benzyloxy)-6-methyl-hepta-1,5-dienyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1,3-dimethyl-butoxy)-silane

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Chemical Property of Triisopropyl-((1S,3S)-4-{(4S,5S)-5-[(1E,5E)-7-(4-methoxy-benzyloxy)-6-methyl-hepta-1,5-dienyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1,3-dimethyl-butoxy)-silane

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Technology Process of Triisopropyl-((1S,3S)-4-{(4S,5S)-5-[(1E,5E)-7-(4-methoxy-benzyloxy)-6-methyl-hepta-1,5-dienyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1,3-dimethyl-butoxy)-silane

There total 13 articles about Triisopropyl-((1S,3S)-4-{(4S,5S)-5-[(1E,5E)-7-(4-methoxy-benzyloxy)-6-methyl-hepta-1,5-dienyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1,3-dimethyl-butoxy)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Acetic acid (E)-2-benzenesulfonyl-1-[(4R,5S)-2,2-dimethyl-5-((2S,4S)-2-methyl-4-triisopropylsilanyloxy-pentyl)-[1,3]dioxolan-4-yl]-7-(4-methoxy-benzyloxy)-6-methyl-hept-5-enyl ester

: 224623-16-9
Triisopropyl-((1S,3S)-4-{(4S,5S)-5-[(1E,5E)-7-(4-methoxy-benzyloxy)-6-methyl-hepta-1,5-dienyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1,3-dimethyl-butoxy)-silane

Guidance literature:: With magnesium oxide; mercury dichloride; In ethanol; for 1.5h; Yield given; Ambient temperature;
DOI:10.1016/S0040-4039(99)00206-3

Reference yield:

: 115-18-4
2-methyl-3-buten-2-ol

: 224623-16-9
Triisopropyl-((1S,3S)-4-{(4S,5S)-5-[(1E,5E)-7-(4-methoxy-benzyloxy)-6-methyl-hepta-1,5-dienyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1,3-dimethyl-butoxy)-silane

Guidance literature:: Multi-step reaction with 12 steps

1: 75 percent / C₆H₁₁COOH / Heating

2: SeO₂ / Heating

3: NaBH₄ / ethanol / 0 °C

4: CSA

5: DIBAL / CH₂Cl₂

6: Et₃N / CH₂Cl₂ / 0 °C

7: NaH / tetrahydrofuran / Ambient temperature

8: (PhSe)2, H₂O₂

9: 1.) n-BuLi / 1.) THF, 15 min, 2.) THF, -78 deg C to room t., 1 h

10: NaBH₄ / ethanol

11: Et₃N, DMAP / CH₂Cl₂

12: Mg(O), HgCl₂ / ethanol / 1.5 h / Ambient temperature

With dmap; sodium tetrahydroborate; n-butyllithium; selenium(IV) oxide; C₆H₁₁COOH; diphenyl diselenide; camphor-10-sulfonic acid; dihydrogen peroxide; magnesium oxide; sodium hydride; diisobutylaluminium hydride; triethylamine; mercury dichloride; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1016/S0040-4039(99)00206-3

Reference yield:

: 42272-93-5
ethyl 5-methyl-4-hexenoate

: 224623-16-9
Triisopropyl-((1S,3S)-4-{(4S,5S)-5-[(1E,5E)-7-(4-methoxy-benzyloxy)-6-methyl-hepta-1,5-dienyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1,3-dimethyl-butoxy)-silane

Guidance literature:: Multi-step reaction with 11 steps

1: SeO₂ / Heating

2: NaBH₄ / ethanol / 0 °C

3: CSA

4: DIBAL / CH₂Cl₂

5: Et₃N / CH₂Cl₂ / 0 °C

6: NaH / tetrahydrofuran / Ambient temperature

7: (PhSe)2, H₂O₂

8: 1.) n-BuLi / 1.) THF, 15 min, 2.) THF, -78 deg C to room t., 1 h

9: NaBH₄ / ethanol

10: Et₃N, DMAP / CH₂Cl₂

11: Mg(O), HgCl₂ / ethanol / 1.5 h / Ambient temperature

With dmap; sodium tetrahydroborate; n-butyllithium; selenium(IV) oxide; diphenyl diselenide; camphor-10-sulfonic acid; dihydrogen peroxide; magnesium oxide; sodium hydride; diisobutylaluminium hydride; triethylamine; mercury dichloride; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1016/S0040-4039(99)00206-3