s-butyl fluoronitro(phenylthio)acetate

Base Information

• Chemical Name: s-butyl fluoronitro(phenylthio)acetate
• CAS No.: 114499-84-2
• Molecular Formula: C₁₂H₁₄FNO₄S
• Molecular Weight: 287.312
• Mol file: 114499-84-2.mol

Synonyms:

Chemical Property of s-butyl fluoronitro(phenylthio)acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of s-butyl fluoronitro(phenylthio)acetate

There total 1 articles about s-butyl fluoronitro(phenylthio)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.2%

ethyl fluoronitro(phenylthio)acetate (100366-14-1) + iso-butanol (78-92-2,15892-23-6) → s-butyl fluoronitro(phenylthio)acetate (114499-84-2,114499-85-3)

Guidance literature:

With titanium(IV) isopropylate; at 100 ℃; for 2h;

Reference yield:

s-butyl fluoronitro(phenylthio)acetate (114499-84-2,114499-85-3) → ethyl fluoronitro(phenylsulphonyl)acetate (114499-83-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 66.4 percent / titanium tetraethoxide / ethanol / 2 h / Heating

2: 77 percent / 80percent m-chloroperbenzoic acid / CH₂Cl₂ / 15 h / Ambient temperature

With titanium(IV) tetraethanolate; 3-chloro-benzenecarboperoxoic acid; In ethanol; dichloromethane;

Reference yield:

s-butyl fluoronitro(phenylthio)acetate (114499-84-2,114499-85-3) → (R)-α-phenylethyl fluoronitro(phenylthio)acetate (100366-36-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 66.4 percent / titanium tetraethoxide / ethanol / 2 h / Heating

2: titanium tetraisopropoxide / 1.5 h / 110 °C

With titanium(IV) isopropylate; titanium(IV) tetraethanolate; In ethanol;

upstream raw materials:

ethyl fluoronitro(phenylthio)acetate

iso-butanol

Downstream raw materials:

ethyl fluoronitro(phenylsulphonyl)acetate

(R)-α-phenylethyl fluoronitro(phenylthio)acetate