(η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride

Base Information

Chemical Name:(η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride
CAS No.:104338-05-8
Molecular Formula:C₁₉H₃₆PRh
Molecular Weight:398.374
Hs Code.:

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Chemical Property of (η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride

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Technology Process of (η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride

There total 1 articles about (η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 84624-03-3
(C₅Me₅)Rh(PMe₃)(H)2

: 110-82-7,25012-93-5
cyclohexane

: 104338-05-8
(η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride

Guidance literature:: In cyclohexane; byproducts: H2; Irradiation (UV/VIS); (N2); 2h; -60°C; removal of cyclohexane (-60°C); NMR;
DOI:10.1021/ja00283a032

Reference yield:

: 104338-05-8
(η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride

: 75-25-2
Bromoform

: 104337-97-5
(η5-methylcyclopentadienyl)(trimethylphosphine)bromocyclohexylrhodium

Guidance literature:: In cyclohexane; (N2); slowly addn. of a CHBr3 soln. in Et2O to a cyclohexane soln. of the Rh-complex below -60°C; agitating and standing at -70°C for 1 h; evapn. in vac.; extn. ( Et2O/hexane); filtration of exts.; removal of solvent; taking up in min. amount of Et2O/hexane; cooling to -40°C; anal. pure;
DOI:10.1021/ja00283a032