(η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride

Base Information

• Chemical Name: (η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride
• CAS No.: 104338-05-8
• Molecular Formula: C₁₉H₃₆PRh
• Molecular Weight: 398.374
• Mol file: 104338-05-8.mol

Synonyms:

Chemical Property of (η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride

There total 1 articles about (η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

(C5Me5)Rh(PMe3)(H)2 (84624-03-3) + cyclohexane (110-82-7,25012-93-5) → (η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride (104338-05-8)

Guidance literature:

In cyclohexane; byproducts: H2; Irradiation (UV/VIS); (N2); 2h; -60°C; removal of cyclohexane (-60°C); NMR;

DOI:10.1021/ja00283a032

Reference yield:

(η5-methylcyclopentadienyl)(trimethylphosphine)(cyclohexyl)rhodium hydride (104338-05-8) + Bromoform (75-25-2) → (η5-methylcyclopentadienyl)(trimethylphosphine)bromocyclohexylrhodium (104337-97-5)

Guidance literature:

In cyclohexane; (N2); slowly addn. of a CHBr3 soln. in Et2O to a cyclohexane soln. of the Rh-complex below -60°C; agitating and standing at -70°C for 1 h; evapn. in vac.; extn. ( Et2O/hexane); filtration of exts.; removal of solvent; taking up in min. amount of Et2O/hexane; cooling to -40°C; anal. pure;

DOI:10.1021/ja00283a032

upstream raw materials:

(C₅Me₅)Rh(PMe₃)(H)2

cyclohexane

Downstream raw materials:

(η5-methylcyclopentadienyl)(trimethylphosphine)bromocyclohexylrhodium