1-tert-Butyl-3-ethyl-3-phenyl-heptylideneamine

Base Information

• Chemical Name: 1-tert-Butyl-3-ethyl-3-phenyl-heptylideneamine
• CAS No.: 115857-95-9
• Molecular Formula: C₁₉H₃₁N
• Molecular Weight: 273.462
• Mol file: 115857-95-9.mol

Synonyms:

Chemical Property of 1-tert-Butyl-3-ethyl-3-phenyl-heptylideneamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-tert-Butyl-3-ethyl-3-phenyl-heptylideneamine

There total 1 articles about 1-tert-Butyl-3-ethyl-3-phenyl-heptylideneamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

tert.-butyl lithium (594-19-4) + 3-Ethyl-3-phenyl-heptanenitrile (115857-89-1) → 1-tert-Butyl-3-ethyl-3-phenyl-heptylideneamine (115857-95-9)

Guidance literature:

In pentane; for 4h; Heating;

DOI:10.1021/jo00254a026

Reference yield: 80.0%

1-tert-Butyl-3-ethyl-3-phenyl-heptylideneamine (115857-95-9) → 5-Ethyl-2,2-dimethyl-5-phenyl-nonan-3-one (115858-02-1)

Guidance literature:

With sulfuric acid; for 4h; Heating;

DOI:10.1021/jo00254a026

Reference yield:

1-tert-Butyl-3-ethyl-3-phenyl-heptylideneamine (115857-95-9) → 3-tert-butyl-2,2-dimethyl-5-ethyl-5-phenyl-3-nonene (115858-27-0)

Guidance literature:

Multi-step reaction with 3 steps

1: 80 percent / 50 wt percent aq. H₂SO₄ / 4 h / Heating

2: 66 percent / pentane / 10 h / Heating

3: KHSO₄ / 24 h / 180 °C

With potassium hydrogensulfate; sulfuric acid; In pentane;

DOI:10.1021/jo00254a026

upstream raw materials:

tert.-butyl lithium

3-Ethyl-3-phenyl-heptanenitrile

Downstream raw materials:

5-Ethyl-2,2-dimethyl-5-phenyl-nonan-3-one

((E)-1-Butyl-1-ethyl-4,4-dimethyl-pent-2-enyl)-benzene

3-tert-butyl-2,2-dimethyl-5-ethyl-5-phenyl-3-nonene

5-Ethyl-2,2-dimethyl-5-phenyl-nonan-3-ol