2,3-{(CO)3Cr(η6-C6H6)CH2}2-2,3-C2B4H6

Base Information

Chemical Name:2,3-{(CO)3Cr(η6-C6H6)CH2}2-2,3-C2B4H6
CAS No.:105472-93-3
Molecular Formula:C₂₂H₂₀B₄Cr₂O₆
Molecular Weight:527.633
Hs Code.:

Synonyms:

Suppliers and Price of 2,3-{(CO)3Cr(η6-C6H6)CH2}2-2,3-C2B4H6

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,3-{(CO)3Cr(η6-C6H6)CH2}2-2,3-C2B4H6

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,3-{(CO)3Cr(η6-C6H6)CH2}2-2,3-C2B4H6

There total 2 articles about 2,3-{(CO)3Cr(η6-C6H6)CH2}2-2,3-C2B4H6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.4%

: 105472-14-8
2,3-dibenzyl-2,3-nido-dicarbahexaborane

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 105472-92-2
2-{(CO)3Cr(η6-C6H6)CH2}-3-(PhCH2)-2,3-C2B4H6

: 105472-93-3
2,3-{(CO)3Cr(η6-C6H6)CH2}2-2,3-C2B4H6

Guidance literature:: In tetrahydrofuran; dibutyl ether; Soln. of reagents in anhydrous dibutyl ether and THF was reflux under dry N2 for 18 h, then cooled to room temp.;; Chromy. on silica gel preparative TLC plates, eluent CH2Cl2-hexane;;

Reference yield:

: Na⁽¹⁺⁾*((C₆H₅CH₂)2C₂B₄H₅)^(1-)

: K⁽¹⁺⁾*((CO)3Cr)2(C₆H₅CH₂)2C₂B₄H₅^(1-)=K((CO)3Cr)2(C₆H₅CH₂)2C₂B₄H₅

: 110015-89-9,110026-54-5
((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

: 105472-93-3
2,3-{(CO)3Cr(η6-C6H6)CH2}2-2,3-C2B4H6

: 105472-95-5
(C₆H₅CH₂)4C₄B₈H₈

Guidance literature:: With oxygen; iron(II) chloride; In tetrahydrofuran; a THF soln. of Cr-containing anion (prepared in vacuo) was filtered onto anhyd. FeCl2 at -78°C, stirred for 1 h at room temp., to this soln. a THF soln. of the other carborane anion was slowly added, mixt. was stirred for 12 h at room temp.; solvent was removed in vacuo, flask was filled with dry N2, opened to air, contents were dissolved in CH2Cl2, O2 was bubbled through the soln. for 12 h, filtered, concd., chromd. of SiO2 plates (CH2Cl2-hexane);