nickel(II) 5,15-diphenyl-10,20-bis(2-trimethylsilylacetilenyl)porphyrinate

Base Information

• Chemical Name: nickel(II) 5,15-diphenyl-10,20-bis(2-trimethylsilylacetilenyl)porphyrinate
• CAS No.: 193265-41-7
• Molecular Formula: C₄₂H₃₆N₄NiSi₂
• Molecular Weight: 711.636
• Mol file: 193265-41-7.mol

Synonyms:

Chemical Property of nickel(II) 5,15-diphenyl-10,20-bis(2-trimethylsilylacetilenyl)porphyrinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of nickel(II) 5,15-diphenyl-10,20-bis(2-trimethylsilylacetilenyl)porphyrinate

There total 3 articles about nickel(II) 5,15-diphenyl-10,20-bis(2-trimethylsilylacetilenyl)porphyrinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

(5-bromo-15-hexyloxy-10,20-diphenylporphyrinato)nickel(II) + trimethylsilylacetylene (1066-54-2) → nickel(II) 5,15-diphenyl-10,20-bis(2-trimethylsilylacetilenyl)porphyrinate (193265-41-7) + [5-hexyloxy-15-(2-trimethylsilylacetylenyl)-10,20-diphenylporphyrinato]nickel(II)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In toluene; for 15h; Inert atmosphere; Reflux;

DOI:10.1002/ejoc.201500628

Reference yield: 57.0%

(5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (193265-36-0) + trimethylsilylacetylene (1066-54-2) → nickel(II) 5,15-diphenyl-10,20-bis(2-trimethylsilylacetilenyl)porphyrinate (193265-41-7)

Guidance literature:

With triethyamine; CuI; (P(C₆H₅)3)2PdCl₂; In triethylamine; addn. of large excess of Me3SiCCH to soln. of Ni complex (in presence ofPd complex and CuI), refluxing (2 h); solvent removal (vac.), repeated column chromy. (CHCl3/hexane), recrystn. (CH2Cl2/MeOH); elem. anal.;

DOI:10.1071/C96193

Reference yield:

5,15-dibromo-10,20-diphenylporphyrin (1057140-05-2,151256-86-9) → nickel(II) 5,15-diphenyl-10,20-bis(2-trimethylsilylacetilenyl)porphyrinate (193265-41-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 1,2-dichloro-ethane

2: triethyamine; CuI; (P(C₆H₅)3)2PdCl₂ / triethylamine

With triethyamine; CuI; (P(C₆H₅)3)2PdCl₂; In 1,2-dichloro-ethane; triethylamine;

DOI:10.1071/C96193

upstream raw materials:

(5,15-dibromo-10,20-diphenylporphyrinato)nickel(II)

trimethylsilylacetylene

5,15-dibromo-10,20-diphenylporphyrin