cis[PtPh₂(1,2-bis(diphenylphosphanyl)methane)]

Base Information

Chemical Name:cis[PtPh₂(1,2-bis(diphenylphosphanyl)methane)]
CAS No.:52621-11-1
Molecular Formula:C₃₇H₃₂P₂Pt
Molecular Weight:733.689
Hs Code.:

cis[PtPh<sub>2</sub>(1,2-bis(diphenylphosphanyl)methane)]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of cis[PtPh₂(1,2-bis(diphenylphosphanyl)methane)]

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Technology Process of cis[PtPh₂(1,2-bis(diphenylphosphanyl)methane)]

There total 5 articles about cis[PtPh₂(1,2-bis(diphenylphosphanyl)methane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 108-86-1,52753-63-6
bromobenzene

: 52595-94-5
dichloro(bis(diphenylphosphino)methane)platinum(II)

: 52621-11-1
cis[PtPh₂(1,2-bis(diphenylphosphanyl)methane)]

Guidance literature:: With magnesium; In diethyl ether; benzene; to the soln. of C6H5MgBr prepared from Mg and C6H5Br in Et2O under N2 the Pt complex and benzene were added, the mixt. was heated under reflux for 1 h; the mixt. was cooled, methanol was added, the solvents were removed in vacuo, extn. with CH2Cl2, crystn. from CH2Cl2-ethanol, elem. anal.;
DOI:10.1039/DT9850001501

Reference yield:

: 287376-85-6
cis,cis-[(C6H5)2Pt(μ-S(CH3)2)(μ-(((C6H5)2P)2CH2)Pt(C6H5)2)]

: 2071-20-7
bis-diphenylphosphinomethane

: 52621-11-1
cis[PtPh₂(1,2-bis(diphenylphosphanyl)methane)]

Guidance literature:: With dimethylsulfide; In chloroform-d1; byproducts: S(CH3)2; the complex was dissolved in CDCl3 and dppm was added, 30 h at 25°C; the presence of excess of S(CH3)2 did not influence on the react.; the solvent was evapd.;
DOI:10.1021/om990784t

Reference yield:

: (1,2,5,6-η4-cycloocta-1,5-diene)diphenylplatinum(II)

: 2071-20-7
bis-diphenylphosphinomethane

: 52621-11-1
cis[PtPh₂(1,2-bis(diphenylphosphanyl)methane)]

Guidance literature:: In chloroform-d1; Pt complex dissolved in CDCl3, org. compd. added as a solid, mixture stirred for 30 min; product not isolated, detected by NMR;
DOI:10.1021/ic50225a005