[(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine^(2-))Fe(III)-⁽¹⁸⁾O-Fe(III)-Cl]B(C₆F₅)4

Base Information

• Chemical Name: [(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine^(2-))Fe(III)-⁽¹⁸⁾O-Fe(III)-Cl]B(C₆F₅)4
• CAS No.: 825638-81-1
• Molecular Formula: C₂₄BF₂₀*C₆₃H₄₀ClF₆Fe₂N₈O₂
• Molecular Weight: 1883.24
• Mol file: 825638-81-1.mol

Synonyms:

Chemical Property of [(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine^(2-))Fe(III)-⁽¹⁸⁾O-Fe(III)-Cl]B(C₆F₅)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine^(2-))Fe(III)-⁽¹⁸⁾O-Fe(III)-Cl]B(C₆F₅)4

There total 1 articles about [(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine^(2-))Fe(III)-⁽¹⁸⁾O-Fe(III)-Cl]B(C₆F₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine(2-))Fe(III)((18)O2)(thf)Fe(II)-Cl]B(C6F5)4 → [(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine(2-))Fe(III)-(18)O-Fe(III)-Cl]B(C6F5)4 (825638-81-1)

Guidance literature:

In tetrahydrofuran; byproducts: (18)O2; (Ar or N2); warming a soln. of iron complex in THF to room temp.;

DOI:10.1021/ja0458773

Reference yield:

FeClN(CH2C5H4N)2CH2C5H3NCH2OC6H4C20H8N4(18)OFe(C6H3F2)3(1+)*B(C6F5)4(1-)=Fe2OCl(CH2C5H3N)3(18)OC27H16N5(C6H3F2)3B(C6F5)4 (825638-81-1) → [(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine(2-))Fe(II)Fe(II)-Cl]B(C6F5)4 (825638-77-5)

Guidance literature:

With triphenylphosphine; In benzene; byproducts: (18)O=P(C6H5)3; Irradiation (UV/VIS); N2; UV-photolysis of benzene-soln. of complex in the presence of P(C6H5)3; detected by spectra;

DOI:10.1021/ic0490932

Downstream raw materials:

[(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine^(2-))Fe(II)Fe(II)-Cl]B(C₆F₅)4