alpha-(2,4,6-Trimethylphenylimino)-O-cresol

Base Information

• Chemical Name: alpha-(2,4,6-Trimethylphenylimino)-O-cresol
• CAS No.: 787-94-0
• Molecular Formula: C16H17NO
• Molecular Weight: 239.317
• European Community (EC) Number: 653-434-3
• DSSTox Substance ID: DTXSID60425472
• Nikkaji Number: J2.202.234B
• Mol file: 787-94-0.mol

Synonyms:787-94-0;2-(Mesityliminomethyl)phenol;ALPHA-(2,4,6-TRIMETHYLPHENYLIMINO)-O-CRESOL;SCHEMBL1949778;DTXSID60425472;6-[(2,4,6-trimethylanilino)methylidene]cyclohexa-2,4-dien-1-one;MFCD00136256;AKOS003671824;N-(Salicylidene)-2,4,6-trimethylaniline

Chemical Property of alpha-(2,4,6-Trimethylphenylimino)-O-cresol

Chemical Property:

• PSA: 29.10000
• LogP: 3.67570
• XLogP3: 4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 239.131014166
• Heavy Atom Count: 18
• Complexity: 277

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)N=CC2=CC=CC=C2O)C

Technology Process of alpha-(2,4,6-Trimethylphenylimino)-O-cresol

There total 3 articles about alpha-(2,4,6-Trimethylphenylimino)-O-cresol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

salicylaldehyde (90-02-8) + 2,4,6-trimethylaniline (88-05-1) → N-2,4,6-trimethylphenylsalicylaldimine (787-94-0)

Guidance literature:

With formic acid; In ethanol; at 80 ℃; Molecular sieve;

DOI:10.1002/pola.29449

Reference yield:

2-methyl-benzyl alcohol (89-95-2) + 2,4,6-trimethylaniline (88-05-1) → N-2,4,6-trimethylphenylsalicylaldimine (787-94-0)

Guidance literature:

In isopropyl alcohol; benzene; Heating;

Reference yield:

→ N-2,4,6-trimethylphenylsalicylaldimine (787-94-0)

Guidance literature:

entspr. Aldehyd, entspr. Amin;

upstream raw materials:

salicylaldehyde

2,4,6-trimethylaniline

2-methyl-benzyl alcohol

Downstream raw materials:

2-[(mesitylamino)methyl]phenol

[Zn(C₆H₄(O)CHNC₆H₂(CH₃)3)2]

2-(N-2,4,6-trimethylphenylsalicylaldimino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Refernces

• 1、 Song, Hayoung,Kim, Hyunho,Lee, Eunsung. "Coumaraz-2-on-4-ylidene: Ambiphilic N-Heterocyclic Carbenes with a Tunable Electronic Structure". supporting information. p. 8603 - 8607. Retrieved 2018/07/14.
• 2、 Clowes, Lucy,Walton, Mark,Redshaw, Carl,Chao, Yimin,Walton, Alex,Elo, Pertti,Sumerin, Victor,Hughes, David L.. "Vanadium(III) phenoxyimine complexes for ethylene or ε-caprolactone polymerization: Mononuclear versus binuclear pre-catalysts". . p. 152 - 160. Retrieved 2013/04/10.