2-o-Tolyl-oxirane

Base Information

• Chemical Name: 2-o-Tolyl-oxirane
• CAS No.: 144923-97-7
• Molecular Formula: C₉H₁₀O
• Molecular Weight: 134.178
• Mol file: 144923-97-7.mol

Synonyms:

Chemical Property of 2-o-Tolyl-oxirane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-o-Tolyl-oxirane

There total 2 articles about 2-o-Tolyl-oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-methyl-2-vinyl-benzene (611-15-4) → 2-o-Tolyl-oxirane (2783-26-8,86457-70-7,144923-97-7) + (-)-o-methylstyrene oxide (86457-70-7)

Guidance literature:

With iodosylbenzene; threitol-strapped manganese porphyrin (3d); 1,5-dicyclohexyl imidazole; In dichloromethane; at 25 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/ja00062a071

Reference yield:

1-methyl-2-vinyl-benzene (611-15-4) → 2-methyl-benzeneacetaldehyde (10166-08-2) + 2-o-Tolyl-oxirane (2783-26-8,86457-70-7,144923-97-7) + (-)-o-methylstyrene oxide (86457-70-7)

Guidance literature:

With chloro<5,10,15,20-tetra(α,β,α,β-o-<(S)-2'-carboxymethyl-1,1'-binaphthyl-2-carboxamido>phenyl)porphinato>iron(III); 1-iodosyl-2,4,6-trimethylbenzene; In toluene; at 0 ℃; for 12h; Product distribution; stereoselectivity, various olefins;

DOI:10.1021/ja00356a016

upstream raw materials:

1-methyl-2-vinyl-benzene