C₂₇H₂₇F₅O₄S

Base Information

Chemical Name:C₂₇H₂₇F₅O₄S
CAS No.:1382088-10-9
Molecular Formula:C₂₇H₂₇F₅O₄S
Molecular Weight:542.567
Hs Code.:

C<sub>27</sub>H<sub>27</sub>F<sub>5</sub>O<sub>4</sub>S

Synonyms:

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Chemical Property of C₂₇H₂₇F₅O₄S

Chemical Property:

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Technology Process of C₂₇H₂₇F₅O₄S

There total 19 articles about C₂₇H₂₇F₅O₄S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1382087-85-5
3β-hydroxyisospongia-13,15-dien-12-one

: 135192-53-9
pentafluorophenoxythiocarbonyl chloride

: 1382088-10-9
C₂₇H₂₇F₅O₄S

Guidance literature:: With dmap; In dichloromethane; at 0 - 20 ℃; for 6h; Inert atmosphere;
DOI:10.1021/jo3008034

Reference yield:

: 1382087-73-1
(1S,3R,4R,6S)-1,3-dimethyl-3-((E)-4-methyl-5-oxohex-3-en-1-yl)-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-2-one

: 1382088-10-9
C₂₇H₂₇F₅O₄S

Guidance literature:: Multi-step reaction with 14 steps

1.1: triethylamine / dichloromethane / 1 h / -78 °C

2.1: 2,6-di-tert-butyl-4-methyl-phenol / toluene; methyloxirane / 168 h / 195 °C / Inert atmosphere

3.1: diethylzinc / hexane / 0.08 h / 0 °C / Inert atmosphere

3.2: 2 h / 0 °C / Inert atmosphere

4.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol; dichloromethane / -30 - 20 °C

5.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / 0 - 20 °C

5.2: 24 h / 50 °C

6.1: 2,2,6,6-tetramethyl-piperidine; n-butyllithium; diethylaluminium chloride / hexane; toluene; benzene / 0.5 h / 0 °C

7.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; p-benzoquinone / dichloromethane / 0.33 h / Reflux

8.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / benzene / 36 h / 20 °C / Inert atmosphere

9.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 0 °C / Molecular sieve; Inert atmosphere

10.1: pyridine hydrogenfluoride / acetonitrile / 24 h / 0 - 20 °C / Inert atmosphere

11.1: sodium hydroxide / 1,4-dioxane; water / 6 h / 90 °C / Inert atmosphere

12.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol; dichloromethane / -65 - 20 °C

13.1: manganese(IV) oxide / chloroform / 72 h / 20 °C

14.1: dmap / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

With 2,2,6,6-tetramethyl-piperidine; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dmap; manganese(IV) oxide; sodium tetrahydroborate; n-butyllithium; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; 2,6-di-tert-butyl-4-methyl-phenol; diethylzinc; diethylaluminium chloride; tetra-(n-butyl)ammonium iodide; sodium hydride; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; p-benzoquinone; sodium hydroxide; In tetrahydrofuran; 1,4-dioxane; methanol; hexane; dichloromethane; chloroform; water; toluene; acetonitrile; methyloxirane; mineral oil; benzene;
DOI:10.1021/jo3008034

Reference yield:

: 1382088-09-6
C₂₀H₂₆O₃

: 1382088-10-9
C₂₇H₂₇F₅O₄S

Guidance literature:: Multi-step reaction with 4 steps

1: sodium hydroxide / 1,4-dioxane; water / 6 h / 90 °C / Inert atmosphere

2: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol; dichloromethane / -65 - 20 °C

3: manganese(IV) oxide / chloroform / 72 h / 20 °C

4: dmap / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

With dmap; manganese(IV) oxide; sodium tetrahydroborate; cerium(III) chloride heptahydrate; sodium hydroxide; In 1,4-dioxane; methanol; dichloromethane; chloroform; water;
DOI:10.1021/jo3008034