chlorido(2-[(4-fluorophenyl)-hydroxy-methyl]-6-methyl-3-(oxo-κO)-pyran-4(1H)-onato-κO4)(eta.6-p-cymene)ruthenium(II)

Base Information

• Chemical Name: chlorido(2-[(4-fluorophenyl)-hydroxy-methyl]-6-methyl-3-(oxo-κO)-pyran-4(1H)-onato-κO4)(eta.6-p-cymene)ruthenium(II)
• CAS No.: 1147104-07-1
• Molecular Formula: C₂₃H₂₄ClFO₄Ru
• Molecular Weight: 519.963
• Mol file: 1147104-07-1.mol

Synonyms:

Chemical Property of chlorido(2-[(4-fluorophenyl)-hydroxy-methyl]-6-methyl-3-(oxo-κO)-pyran-4(1H)-onato-κO4)(eta.6-p-cymene)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorido(2-[(4-fluorophenyl)-hydroxy-methyl]-6-methyl-3-(oxo-κO)-pyran-4(1H)-onato-κO4)(eta.6-p-cymene)ruthenium(II)

There total 1 articles about chlorido(2-[(4-fluorophenyl)-hydroxy-methyl]-6-methyl-3-(oxo-κO)-pyran-4(1H)-onato-κO4)(eta.6-p-cymene)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 2-((4-fluorophenyl)-hydroxy-methyl)-3-hydroxy-6-methyl-pyran-4(1H)-one (1147104-02-6) → chlorido(2-[(4-fluorophenyl)-hydroxy-methyl]-6-methyl-3-(oxo-κO)-pyran-4(1H)-onato-κO4)(eta.6-p-cymene)ruthenium(II) (1147104-07-1)

Guidance literature:

With NaOCH₃; In methanol; dichloromethane; mixt. of ligand and NaOMe in methanol was stirred for 5 min under inert atm.; soln. of Ru complex in CH2Cl2 was added dropwise; stirred for 5 h; concd. (vac.); extd. (CH2Cl2); org. layer filtered; solvent removed; recrystd. (EtOAc/Et2O/hexane); elem. anal.;

DOI:10.1016/j.jorganchem.2008.10.016

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

2-((4-fluorophenyl)-hydroxy-methyl)-3-hydroxy-6-methyl-pyran-4(1H)-one