Allyl-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-2-phthalimido-β-D-glucopyranosid

Base Information

Chemical Name:Allyl-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-2-phthalimido-β-D-glucopyranosid
CAS No.:104039-83-0
Molecular Formula:C₅₈H₅₇NO₁₂
Molecular Weight:960.09
Hs Code.:

Synonyms:

Suppliers and Price of Allyl-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-2-phthalimido-β-D-glucopyranosid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Allyl-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-2-phthalimido-β-D-glucopyranosid

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Allyl-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-2-phthalimido-β-D-glucopyranosid

There total 10 articles about Allyl-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-2-phthalimido-β-D-glucopyranosid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 51450-24-9
hexa-O-acetyl-D-lactal

: 104039-83-0,118760-06-8
Allyl-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-2-phthalimido-β-D-glucopyranosid

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) Ce(NO₃)4*2NH₄NO₃, NaN₃, 2.) LiNO₃ / 2.) acetonitrile, DMF, 2 d, room temp.

2: 33 percent / Na / 0.25 h

3: 4.7 g / p-toluenesulfonic / acetonitrile / 3 h / Ambient temperature

4: 4.40 g / NaH / dimethylformamide / 2 h / Ambient temperature

5: 75 percent / H₂S / pyridine; H₂O / 4.5 h / 60 °C

6: 4.05 g / 5percent HCl / methanol / pH 3-4

7: 3.88 g / Amberlite IRA-400, OH^(1-) / methanol

8: 1.) Et₃N, 2.) acetic anhydride / 1.) 16 h, room temp., 2.) 18 h, room temp., ca. 90 min, 90 deg C

With ammonium nitrate; hydrogenchloride; cerium nitrate; sodium azide; Amberlite IRA-400; hydrogen sulfide; lithium nitrate; hydroxide; sodium; acetic anhydride; sodium hydride; toluene-4-sulfonic acid; triethylamine; In pyridine; methanol; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0008-6215(00)90670-0

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 104039-83-0,118760-06-8
Allyl-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-2-phthalimido-β-D-glucopyranosid

Guidance literature:: Multi-step reaction with 6 steps

1: 4.7 g / p-toluenesulfonic / acetonitrile / 3 h / Ambient temperature

2: 4.40 g / NaH / dimethylformamide / 2 h / Ambient temperature

3: 75 percent / H₂S / pyridine; H₂O / 4.5 h / 60 °C

4: 4.05 g / 5percent HCl / methanol / pH 3-4

5: 3.88 g / Amberlite IRA-400, OH^(1-) / methanol

6: 1.) Et₃N, 2.) acetic anhydride / 1.) 16 h, room temp., 2.) 18 h, room temp., ca. 90 min, 90 deg C

With hydrogenchloride; Amberlite IRA-400; hydrogen sulfide; hydroxide; acetic anhydride; sodium hydride; toluene-4-sulfonic acid; triethylamine; In pyridine; methanol; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0008-6215(00)90670-0

Reference yield:

: 68733-24-4
O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl bromide

: 104039-83-0,118760-06-8
Allyl-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-2-phthalimido-β-D-glucopyranosid

Guidance literature:: Multi-step reaction with 8 steps

1: 58 percent / silversilicate, molecular sieve (4 Angstroem) / CH₂Cl₂; toluene / 1.) -15 deg C, 15 h, 2.) room temp., 2 d

2: 91 percent / NaOMe / methanol / 1 h

3: 4.7 g / p-toluenesulfonic / acetonitrile / 3 h / Ambient temperature

4: 4.40 g / NaH / dimethylformamide / 2 h / Ambient temperature

5: 75 percent / H₂S / pyridine; H₂O / 4.5 h / 60 °C

6: 4.05 g / 5percent HCl / methanol / pH 3-4

7: 3.88 g / Amberlite IRA-400, OH^(1-) / methanol

8: 1.) Et₃N, 2.) acetic anhydride / 1.) 16 h, room temp., 2.) 18 h, room temp., ca. 90 min, 90 deg C

With hydrogenchloride; silversilicate; 4 A molecular sieve; Amberlite IRA-400; hydrogen sulfide; hydroxide; sodium methylate; acetic anhydride; sodium hydride; toluene-4-sulfonic acid; triethylamine; In pyridine; methanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1016/S0008-6215(00)90670-0