(4R,5R,4'R)-5-[(R)-2-((Z)-13-Cyclohexyl-tridec-12-enyloxy)-1-((E)-13-cyclohexyl-tridec-12-enyloxy)-ethyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]

Base Information

Chemical Name:(4R,5R,4'R)-5-[(R)-2-((Z)-13-Cyclohexyl-tridec-12-enyloxy)-1-((E)-13-cyclohexyl-tridec-12-enyloxy)-ethyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]
CAS No.:203244-63-7
Molecular Formula:C₅₀H₉₀O₆
Molecular Weight:787.261
Hs Code.:

(4R,5R,4'R)-5-[(R)-2-((Z)-13-Cyclohexyl-tridec-12-enyloxy)-1-((E)-13-cyclohexyl-tridec-12-enyloxy)-ethyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]

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Chemical Property of (4R,5R,4'R)-5-[(R)-2-((Z)-13-Cyclohexyl-tridec-12-enyloxy)-1-((E)-13-cyclohexyl-tridec-12-enyloxy)-ethyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]

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Technology Process of (4R,5R,4'R)-5-[(R)-2-((Z)-13-Cyclohexyl-tridec-12-enyloxy)-1-((E)-13-cyclohexyl-tridec-12-enyloxy)-ethyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]

There total 5 articles about (4R,5R,4'R)-5-[(R)-2-((Z)-13-Cyclohexyl-tridec-12-enyloxy)-1-((E)-13-cyclohexyl-tridec-12-enyloxy)-ethyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 112999-97-0,88517-92-4
2-[(12-bromododecyl)oxy]tetrahydro-2H-pyran

: 203244-63-7
(4R,5R,4'R)-5-[(R)-2-((Z)-13-Cyclohexyl-tridec-12-enyloxy)-1-((E)-13-cyclohexyl-tridec-12-enyloxy)-ethyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]

Guidance literature:: Multi-step reaction with 4 steps

1: 48 percent / KOH / toluene / 24 h / Heating

2: 81 percent / camphorsulphonic acid / CH₂Cl₂; methanol / 11 h / Ambient temperature

3: 82 percent / pyridinium chlorochromate / CH₂Cl₂ / 1 h / Ambient temperature

4: 1.) n-BuLi / 1.) hexane, THF, 0 deg C, 30 min, 2.) hexane, THF, 0 deg C, 30 min

With potassium hydroxide; n-butyllithium; camphor-10-sulfonic acid; pyridinium chlorochromate; In methanol; dichloromethane; toluene;
DOI:10.1248/cpb.45.2085

Reference yield:

: 203244-61-5
12-[(R)-2-(12-Hydroxy-dodecyloxy)-1-((4R,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethoxy]-dodecan-1-ol

: 203244-63-7
(4R,5R,4'R)-5-[(R)-2-((Z)-13-Cyclohexyl-tridec-12-enyloxy)-1-((E)-13-cyclohexyl-tridec-12-enyloxy)-ethyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / pyridinium chlorochromate / CH₂Cl₂ / 1 h / Ambient temperature

2: 1.) n-BuLi / 1.) hexane, THF, 0 deg C, 30 min, 2.) hexane, THF, 0 deg C, 30 min

With n-butyllithium; pyridinium chlorochromate; In dichloromethane;
DOI:10.1248/cpb.45.2085

Reference yield:

: 203244-60-4
(4R,5R,4'R)-5-{(R)-1,2-Bis-[12-(tetrahydro-pyran-2-yloxy)-dodecyloxy]-ethyl}-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]

: 203244-63-7
(4R,5R,4'R)-5-[(R)-2-((Z)-13-Cyclohexyl-tridec-12-enyloxy)-1-((E)-13-cyclohexyl-tridec-12-enyloxy)-ethyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]

Guidance literature:: Multi-step reaction with 3 steps

1: 81 percent / camphorsulphonic acid / CH₂Cl₂; methanol / 11 h / Ambient temperature

2: 82 percent / pyridinium chlorochromate / CH₂Cl₂ / 1 h / Ambient temperature

3: 1.) n-BuLi / 1.) hexane, THF, 0 deg C, 30 min, 2.) hexane, THF, 0 deg C, 30 min

With n-butyllithium; camphor-10-sulfonic acid; pyridinium chlorochromate; In methanol; dichloromethane;
DOI:10.1248/cpb.45.2085