cis-(Os(bpy)2(p-cinn)2)(PF₆)2

Base Information

• Chemical Name: cis-(Os(bpy)2(p-cinn)2)(PF₆)2
• CAS No.: 85717-52-8
• Molecular Formula: C₄₈H₄₀N₈O₂Os*2F₆P
• Molecular Weight: 1241.03
• Mol file: 85717-52-8.mol

Synonyms:

Chemical Property of cis-(Os(bpy)2(p-cinn)2)(PF₆)2

Chemical Property:

Purity/Quality:

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Technology Process of cis-(Os(bpy)2(p-cinn)2)(PF₆)2

There total 1 articles about cis-(Os(bpy)2(p-cinn)2)(PF₆)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

ammonium hexafluorophosphate + cis-Os(bpy)2(CO3)*2H2O (81831-23-4) + N-(pyridin-4-yl)cinnamamide (85649-70-3) → cis-(Os(bpy)2(p-cinn)2)(PF6)2 (85717-52-8)

Guidance literature:

With trifluoroacetic acid; In butan-1-ol; deoxygenated suspn. cis-Os(bpy)2(CO3)*2H2O in n-butanol plus CF3COOH gently heated with stirring for 30 min, 10-fold excess p-cinn added and react. mixt. refluxed for 4 h, aq. soln. NH4PF6 added; ppt. collected and chromed. (1:1 toluene/CH3CN), complex repptd. from CH2Cl2 into ether, filtered and dried;

Reference yield:

cis-(Os(bpy)2(p-cinn)2)(PF6)2 (85717-52-8) → (Os(bpy)2(p-cinn)2)(PF6)2(polymer) (85717-41-5)

Guidance literature:

In acetonitrile; Electrochem. Process; electropolymerization complex in CH3CN-saturated nitrogen soln. by scanning Pt-disk potential repeatedly ca. 150 mV past E1/2 for the reductionwave of interest;

upstream raw materials:

cis-Os(bpy)2(CO₃)*2H₂O

N-(pyridin-4-yl)cinnamamide

Downstream raw materials:

(Os(bpy)2(p-cinn)2)(PF₆)2(polymer)