RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=(RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2)PF₆

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Chemical Name:RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=(RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2)PF₆
CAS No.:131931-10-7
Molecular Formula:C₄₉H₃₉As₂N₄ORu*F₆P
Molecular Weight:1095.75
Hs Code.:

RuH(CO)(C<sub>5</sub>H<sub>4</sub>NCN)2(As(C<sub>6</sub>H<sub>5</sub>)3)2<sup>(1+)</sup>*PF<sub>6</sub><sup>(1-)</sup>=(RuH(CO)(C<sub>5</sub>H<sub>4</sub>NCN)2(As(C<sub>6</sub>H<sub>5</sub>)3)2)PF<sub>6</sub>

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Chemical Property of RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=(RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2)PF₆

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Technology Process of RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=(RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2)PF₆

There total 1 articles about RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=(RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2)PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 100-48-1
pyridine-4-carbonitrile

: ammonium hexafluorophosphate

: 75455-74-2,130061-85-7
[ruthenium(II)(hydride)(chloride)(carbonyl)(triphenylarsine)3]

: 131931-10-7
RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=(RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2)PF₆

Guidance literature:: In methanol; benzene; heating of a soln. of 4-CNPy and Ru-complex in C6H6 under reflux for 4.5 h, cooling to room temp., filtration, concentration under reduced pressure (vol. to ca 5 cm**3), addn. of a soln. of the suitable anion salt in CH3OH, crystn. during 10 h; centrifugation, washing with CH3OH, then H2O, then CH3OH, then diethyl ether, drying in vac.; elem. anal.;
DOI:10.1016/S0277-5387(00)84047-4

Reference yield: 50.0%

: ammonium hexafluorophosphate

: [Ru(η5-cyclopentadienyl)(triphenylarsine)2Cl]

: 131931-10-7
RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=(RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2)PF₆

: {H(CO)(AsPh3)2(4-cyanopyridine)Ru-μ-(4-cyanopyridine)-Ru(η5-C5H5)(AsPh3)2}(PF6)2

Guidance literature:: In methanol; heating of a suspn. of Ru-NCPy-complex and Ru-C5H5-complex in CH3OH under reflux for ca 5 h, cooling to room temp., filtration, concentration under reduced pressure (vol. to ca 5 cm**3), addn. of a soln. of the suitable anion salt in CH3OH; sepn. of crystalline compd. by filtration, washing with CH3OH, then H2O, then CH3OH, then diethyl ether, drying in vac.; elem. anal.;
DOI:10.1016/S0277-5387(00)84047-4