cobalt trifluoroacetate

Base Information

• Chemical Name: cobalt trifluoroacetate
• CAS No.: 24517-83-7
• Molecular Formula: 2C₂F₃O₂*Co
• Molecular Weight: 285.025
• Mol file: 24517-83-7.mol

Synonyms:

Chemical Property of cobalt trifluoroacetate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of cobalt trifluoroacetate

There total 3 articles about cobalt trifluoroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Co(III) trifluoroacetate → trifluoroacetic acid-methyl ester (431-47-0) + cobalt trifluoroacetate (6185-58-6,24517-83-7,50517-80-1) + trifluoroacetic acid (76-05-1)

Guidance literature:

With methane; In trifluoroacetic acid; React. between CH4 and Co-compd. in CF3COOH soln. is carried out at 30 atm of initial CH4 and 180°C (3 h).; Identification of CF3COOMe by GLC anal. and PMR spectroscopy.;

DOI:10.1039/c39900001049

Reference yield: 77.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + (CO)3(η5-C5H4Me)WCH2CCC6H4-p-Me + trifluoroacetic acid (76-05-1) → (CO)3Co(μ-p-MeC6H4CCMe)W(η5-C5H4Me)(CO)2 + cobalt trifluoroacetate (6185-58-6,24517-83-7,50517-80-1)

Guidance literature:

In pentane; (Ar, dry solvents); addn. of W compd. in pentane to stirring soln. of Co2(CO)8 in pentane at room temperature over 3 min, addn. of CF3COOH after 40 min, stirring (12 h); filtration, chromy. of filtrate (alumina, pentane); detn. of Co(CF3COO)2 by IR spectroscopy;

DOI:10.1016/0022-328X(90)85103-6

Reference yield: 44.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + (CO)3(η5-C5H4Me)WCH2CCPh + trifluoroacetic acid (76-05-1) → (CO)3Co(μ-PhCCMe)W(η5-C5H4Me)(CO)2 + cobalt trifluoroacetate (6185-58-6,24517-83-7,50517-80-1)

Guidance literature:

In pentane; (Ar, dry solvents); addn. of W compd. in pentane to stirring soln. of Co2(CO)8 in pentane at room temperature over 3 min, addn. of CF3COOH after 40 min, stirring (12 h); filtration, chromy. of filtrate (alumina, pentane); detn. of Co(CF3COO)2 by IR spectroscopy;

DOI:10.1016/0022-328X(90)85103-6

upstream raw materials:

dicobalt octacarbonyl

trifluoroacetic acid