heptahydridobis(trimethylphosphine)rhenium(VII)-aniline(1/1)

Base Information

• Chemical Name: heptahydridobis(trimethylphosphine)rhenium(VII)-aniline(1/1)
• CAS No.: 86664-99-5
• Molecular Formula: C₆H₇N*C₆H₂₅P₂Re
• Molecular Weight: 438.547
• Mol file: 86664-99-5.mol

Synonyms:

Chemical Property of heptahydridobis(trimethylphosphine)rhenium(VII)-aniline(1/1)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of heptahydridobis(trimethylphosphine)rhenium(VII)-aniline(1/1)

There total 1 articles about heptahydridobis(trimethylphosphine)rhenium(VII)-aniline(1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.2%

lithium aluminium tetrahydride (16853-85-3) + {Re(NC6H5)Cl3(P(CH3)3)2} → Re2H8(trimethylphosphine)4 + heptahydridobis(trimethylphosphine)rhenium(VII)-aniline(1/1) (86664-99-5)

Guidance literature:

In diethyl ether; to suspn. of Re(NPh)(PMe3)2Cl3 in Et2O under Ar was added LiAlH4, stirred at room temp. for 1 h, cooled to -78°C, methanol/Et2O (1:1) added over 30 min (stirring), stirred for 1 h at -78°C, allowed to warm to room temp., stirred for 1 h; mixt. centrifuged, soln. evapd., residue extd. with hexane, soln. reduced and cooled, fractional crystn. from hexane; elem. anal.;

DOI:10.1039/DT9850000587

upstream raw materials:

lithium aluminium tetrahydride