RhS₂COCH₃(CO)P(C₆H₄Cl)3

Base Information

Chemical Name:RhS₂COCH₃(CO)P(C₆H₄Cl)3
CAS No.:112388-55-3
Molecular Formula:C₂₁H₁₅Cl₃O₂PRhS₂
Molecular Weight:603.719
Hs Code.:

RhS<sub>2</sub>COCH<sub>3</sub>(CO)P(C<sub>6</sub>H<sub>4</sub>Cl)3

Synonyms:

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Chemical Property of RhS₂COCH₃(CO)P(C₆H₄Cl)3

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Technology Process of RhS₂COCH₃(CO)P(C₆H₄Cl)3

There total 1 articles about RhS₂COCH₃(CO)P(C₆H₄Cl)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 112388-54-2
Rh(CO)2S₂COCH₃

: 1159-54-2
tri(4-chlorophenyl)phosphine

: 112388-55-3
RhS₂COCH₃(CO)P(C₆H₄Cl)3

Guidance literature:: In toluene; (N2); to soln. of Rh complex was added the phosphine (1:1 mol) and stirred for 30 min; soln. was evapd. to dryness, residual oil was taken up in Et2O (or CH2Cl2) and pptd. with hexane; elem. anal.;
DOI:10.1016/0022-328X(87)85138-0

Reference yield:

: 112388-55-3
RhS₂COCH₃(CO)P(C₆H₄Cl)3

: 112388-61-1
RhI₂(S₂COCH₃)(CO)P(C₆H₄Cl)3

Guidance literature:: With I₂; In toluene; (N2); slight excess of I2 was added to soln. of Rh complex and stirred for 2 h at room temp.; addn. of cold Et2O and hexane gave ppt. which was filtered off, washed with hexane and dried in vac.; elem. anal.;
DOI:10.1016/0022-328X(87)85138-0

Reference yield:

: 112388-55-3
RhS₂COCH₃(CO)P(C₆H₄Cl)3

: RhI(S₂COCH₃)CH₃CO(P(C₆H₄Cl)3)

Guidance literature:: With CH₃I; In toluene; (N2); excess of MeI was added to soln. of Rh complex and mixt. was stirred for 4 h; concd. soln. was pptd. with cold Et2O and hexane; elem. anal.;
DOI:10.1016/0022-328X(87)85138-0