(2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one

Base Information

Chemical Name:(2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one
CAS No.:133800-68-7
Molecular Formula:C₄₆H₇₄O₈Si
Molecular Weight:783.174
Hs Code.:

(2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one

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Suppliers and Price of (2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one

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Chemical Property of (2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one

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Technology Process of (2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one

There total 1 articles about (2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 114114-23-7
(4R,6R)-6-Benzyloxy-4-methyl-6-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-heptan-3-one

: 133782-37-3
(2S,3R)-2-<(benzyloxy)methoxy>-3-<(tert-butyldimethylsilyl)oxy>-2-methylpentanal

: 133800-68-7
(2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one

Guidance literature:: With n-butyllithium; 1,1,1,3,3,3-hexamethyl-disilazane; Yield given. Multistep reaction; 1) THF, hexane, 3 h, -60 deg C 2) THF, 15 min, -78 deg C;
DOI:10.1016/S0040-4020(01)96140-X

Reference yield:

: 133800-68-7
(2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one

: (2R,4R,6R,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecane-5,7-diol

Guidance literature:: With lithium tri-t-butoxyaluminum hydride; In diethyl ether; Yield given;
DOI:10.1016/S0040-4020(01)96140-X

Reference yield:

: 133800-68-7
(2R,4R,6S,7S,8S,9R)-2-Benzyloxy-8-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-4,6,8-trimethyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-undecan-5-one

: 133782-47-5,133814-79-6
[(1R,2S)-2-Benzyloxymethoxy-2-((4S,5R,6R)-6-{(1R,3R)-3-benzyloxy-1-methyl-3-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-ethyl-propoxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH(t-BuO)3 / diethyl ether

2: DMP, (+/-)-10-camphorosulfonic acid

With phthalic acid dimethyl ester; 10-camphorsufonic acid; lithium tri-t-butoxyaluminum hydride; In diethyl ether;
DOI:10.1016/S0040-4020(01)96140-X