(CH₃)3SnC(CH₂(CH)3(CH₂)3)CSn(CH₃)3CO₂CH₃

Base Information

• Chemical Name: (CH₃)3SnC(CH₂(CH)3(CH₂)3)CSn(CH₃)3CO₂CH₃
• CAS No.: 104803-50-1
• Molecular Formula: C₁₇H₃₂O₂Sn₂
• Molecular Weight: 505.86
• Mol file: 104803-50-1.mol

Synonyms:

Chemical Property of (CH₃)3SnC(CH₂(CH)3(CH₂)3)CSn(CH₃)3CO₂CH₃

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (CH₃)3SnC(CH₂(CH)3(CH₂)3)CSn(CH₃)3CO₂CH₃

There total 3 articles about (CH₃)3SnC(CH₂(CH)3(CH₂)3)CSn(CH₃)3CO₂CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(CH3)3SnC(CH2(CH)3(CH2)3)CSn(CH3)3CO2CH3 (80866-57-5,104803-50-1) → (CH3)3SnC(CH2(CH)3(CH2)3)CSn(CH3)3CO2CH3 (80866-57-5,104803-50-1)

Guidance literature:

In neat (no solvent); Ar; heated at 88°C for 48 h; distilled (150°C/0.05 Torr); elem. anal.;

Reference yield: 74.0%

C6H9CH2C2CO2CH3 (122244-77-3) + hexamethyldistannane (661-69-8) → (CH3)3SnC(CH2(CH)3(CH2)3)CSn(CH3)3CO2CH3 (80866-57-5,104803-50-1)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; Ar; stoich., refluxed for 3 h; concd., chromy. (silica gel, petroleum ether/Et2O), dried (0.05 Torr, room temp., 1-2 h); elem. anal.;

Reference yield:

hexamethyldistannane (661-69-8) + methyl 4-(3-cyclohexenyl)-2-butynoate (80866-50-8) → (CH3)3SnC(CH2(CH)3(CH2)3)CSn(CH3)3CO2CH3 (80866-57-5,104803-50-1)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; a soln. of the acetylenic ester, (Me3Sn)2 and the catalyst (molar ratio1:1:0.01 resp.) was refluxed for 4-6 h; spectral data (the kind of spectra not indicated) confirm the structure; high-resolution mass spectrometry exhibit satisfactory molecular mass detn.;

DOI:10.1039/c39860000626

upstream raw materials:

C₆H₉CH₂C₂CO₂CH₃

hexamethyldistannane

methyl 4-(3-cyclohexenyl)-2-butynoate

(CH₃)3SnC(CH₂(CH)3(CH₂)3)CSn(CH₃)3CO₂CH₃

Downstream raw materials:

(CH₃)3SnC(CH₂(CH)3(CH₂)3)CSn(CH₃)3CO₂CH₃