(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Base Information

Chemical Name:(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS No.:99143-48-3
Molecular Formula:BF₄*CH₄O*C₄₃H₄₅NP₂Rh
Molecular Weight:859.537
Hs Code.:
European Community (EC) Number:635-579-4
DSSTox Substance ID:DTXSID20704836
Mol file:99143-48-3.mol

Synonyms:(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;99143-48-3;[(3R,4R)-1-benzyl-4-diphenylphosphanylpyrrolidin-3-yl]-diphenylphosphane;cycloocta-1,5-diene;rhodium;tetrafluoroborate;DTXSID20704836;BP-12244;(+)-(3R,4R)-Bis(diphenylphosphino)-1-benzylpyrrolidine(1,5-cyclooctadiene)rhodium(i)tetrafluoroborate;(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98%

Suppliers and Price of (+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

BLDpharm
(3R,4R)-(+)-Bis(diphenylphosphino)-1-benzylpyrrolidine(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98%
100mg
$ 164.00

Arctom
(3R,4R)-(+)-Bis(diphenylphosphino)-1-benzylpyrrolidine(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98%
100mg
$ 142.00

American Custom Chemicals Corporation
(3R,4R)-(+)-BIS(DIPHENYLPHOSPHINO)-1-BENZYLPYRROLIDINE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE 95.00%
500MG
$ 1002.95

American Custom Chemicals Corporation
(3R,4R)-(+)-BIS(DIPHENYLPHOSPHINO)-1-BENZYLPYRROLIDINE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE 95.00%
100MG
$ 660.70

Total 5 raw suppliers

Chemical Property of (+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Chemical Property:

PSA：30.42000
LogP:10.12070
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:8
Exact Mass:827.21114
Heavy Atom Count:52
Complexity:675

Purity/Quality:

97% ^*data from raw suppliers

(3R,4R)-(+)-Bis(diphenylphosphino)-1-benzylpyrrolidine(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:[B-](F)(F)(F)F.C1CC=CCCC=C1.C1C(C(CN1CC2=CC=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6.[Rh]
Isomeric SMILES:[B-](F)(F)(F)F.C1CC=CCCC=C1.C1[C@H]([C@@H](CN1CC2=CC=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6.[Rh]

Technology Process of (+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

There total 1 articles about (+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate

: 99135-95-2
(R,R)-(+)-N-benzyl-3,4-bis(diphenylphosphino)pyrrolidine

: 99143-48-3
[(3R,4R)-1-benzyl-3,4-bis(diphenylphosphino)pyrrolidine-P,P'](1,5-cyclooctadiene)rhodium-tetrafluoroborate * methanol

Guidance literature:: With methanol; In dichloromethane; (N2), dissolved compounds mixed, stirred for 2 h; volume reduced, CH2Cl2 removed, CH3OH added, precipitated with Et2O, centrifuged, washed with Et2O, dried in vac.; elem. anal.;