[(PdMe)2(μ-κ2(P,P)Cy2PCH2PCy2)2(μ-F)][SiMeF4

Base Information

• Chemical Name: [(PdMe)2(μ-κ2(P,P)Cy2PCH2PCy2)2(μ-F)][SiMeF4
• CAS No.: 869676-57-3
• Molecular Formula: CH₃F₄Si*C₅₂H₉₈FP₄Pd₂
• Molecular Weight: 1198.2
• Mol file: 869676-57-3.mol

Synonyms:

Chemical Property of [(PdMe)2(μ-κ2(P,P)Cy2PCH2PCy2)2(μ-F)][SiMeF4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(PdMe)2(μ-κ2(P,P)Cy2PCH2PCy2)2(μ-F)][SiMeF4

There total 2 articles about [(PdMe)2(μ-κ2(P,P)Cy2PCH2PCy2)2(μ-F)][SiMeF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

Pentafluoropyridine (700-16-3) + (bis(dicyclohexylphosphino)methane)dimethylpalladium(II) (343987-35-9) + water (7732-18-5) → [(PdMe)2(μ-κ2(P,P)Cy2PCH2PCy2)2(μ-F)][SiMeF4 (869676-57-3) + [(PdMe)2(μ-κ2(P,P)Cy2PCH2PCy2)2(μ-F)][OC5NF4] (869749-37-1)

Guidance literature:

With glass; In toluene; under N2; Pd-contg. compd. (0.77 mmol) was suspended in toluene and a C5F5N (0.92 mmol) was added; the mixt. was stirred for 7 d at room temp.; in glass NMR tube; soln. was filtered; the solid was washed with toluene and dried in vac.;elem. anal.;

DOI:10.1039/b509032f

Reference yield:

(bis(dicyclohexylphosphino)methane)dimethylpalladium(II) (343987-35-9) + 2,4,6-trifluoropyrimidine (696-82-2) → [(PdMe)2(μ-κ2(P,P)Cy2PCH2PCy2)2(μ-F)][SiMeF4 (869676-57-3)

Guidance literature:

With glass; In not given; under N2; by a react. of Pd-contg. compd. with 2,4,6-trifluoropyrimidine; a number of addnl. org. compds. was also obtained;

DOI:10.1039/b509032f

upstream raw materials:

Pentafluoropyridine

(bis(dicyclohexylphosphino)methane)dimethylpalladium(II)

water

2,4,6-trifluoropyrimidine

Refernces